Sol-Gel Entrapped TPAP: An Off-the-Shelf Catalyst Set for the Clean Oxidation of Alcohols

Author(s): Mario Pagliaro, Rosaria Ciriminna, Massimo Carraro, Sandro Campestrini.

Journal Name: Current Organic Chemistry

Volume 12 , Issue 3 , 2008

Abstract:

Whether in supercritical CO2 or in organic solvent and using O2 or aqueous H2O2 as primary oxidants, the series of sol-gel entrapped TPAP hybrid silica gels is a versatile class of oxidation catalysts suitable for the highly selective conversion of alcohols to carbonyls. These materials are generally more stable and active than traditional polymersupported analogues. This report summarizes recent findings showing the large potential of this technology for synthetic chemistry.

Keywords: oxoruthenate catalyst, dehydrogenation, FluoRuGel, aerobic oxidation, sol-gel process

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Article Details

VOLUME: 12
ISSUE: 3
Year: 2008
Page: [257 - 261]
Pages: 5
DOI: 10.2174/138527208783497466
Price: $58

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