Abstract
This account is devoted to a discussion of synthetic applications of olefin metathesis in carbohydrate chemistry. Olefin metathesis has emerged as a highly promising and exciting area in the contemporary organic synthesis of carbon-carbon bonds. Metathetic ring-closure (RCM) of diene precursors is advancing into one of the most useful and frequently applied transformations in modern organic chemistry. The development has been particularly rapid in recent years following the introduction of efficient transition metal carbene catalysts as reflected by the number of reviews on the general field of olefin metathesis in recent years. Cross-metathesis of suitably functionalized carbohydrates with well-defined metal carbene complexes is yet another of the big promises in carbohydrate synthesis for years to come. Compared with the ringclosing metathesis, this variation of the theme has, to date, received much less attention from the scientific community despite the fact that it has proved to be of tremendous synthetic value in the area of organometallic chemistry.
Call for Papers in Thematic Issues
Advances of Heterocyclic Chemistry with Pesticide Activity
Global food safety and security will continue to be a global concern for the next 50 years and beyond. Plant diseases have had a significant impact on food safety and security throughout the entire food chain, from primary production to consumption. While conventional chemical pesticides have been traditionally used for ...read more
Calculation design of covalent/metal organic framework based catalysts
This research area combines theoretical computation and screening with machine learning for the design of covalent/metal organic framework-based catalysts, bridging the disciplines of organic chemistry, physical chemistry, computational chemistry, materials science, and machine learning. It covers several critical aspects: designing and synthesizing organic catalysts for improved performance, applying computational methods ...read more
Carbohydrates conversion in biofuels and bioproducts
Biomass pretreatment, hydrolysis, and saccharification of carbohydrates, and sugars bioconversion in biofuels and bioproducts within a biorefinery framework. Carbohydrates derived from woody biomass, agricultural wastes, algae, sewage sludge, or any other lignocellulosic feedstock are included in this issue. Simulation, techno-economic analysis, and life cycle analysis of a biorefinery process are ...read more
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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