(4+3)Cycloaddition Reactions Cycloaddition of Metal Oxyallyl Cations Generated from alph,alpha-Di- and alph,alpha-Poly-Haloketones to 1,3-Dienes and Anthracenes

Author(s): Abd El-Wareth , A. O. Sarhan .

Journal Name: Current Organic Chemistry

Volume 5 , Issue 7 , 2001

Become EABM
Become Reviewer

Abstract:

The (4+3)cyclocoupling reaction of allyl cations to 1,3-dienes is an efficient and easy route for the stereoselective synthesis of seven-membered ring compounds. Annulations using these species have opened easy access to a wide range of organic frameworks that have been utilized in the synthesis of natural products, pharmacologically active compounds and key intermediates for various useful organic and alkaloid compounds.

Keywords: Cycloaddition Reactions, Cycloaddition, Metal Oxyallyl Cations, Poly-Haloketones, 1,3-Dienes, Anthracenes, Cyclopropanones, Acyclic Dienes

Rights & PermissionsPrintExport Cite as

Article Details

VOLUME: 5
ISSUE: 7
Year: 2001
Page: [827 - 844]
Pages: 18
DOI: 10.2174/1385272013375184
Price: $58

Article Metrics

PDF: 4