Abstract
Recent developments in ruthenium-catalyzed chemo-, regio-, and stereoselective C-C bond forming reactions as well as a C-C bond cleaving reaction via an η3-allylruthenium intermediate are disclosed, in which novel ambiphilic reactivity of η3-allylruthenium complexes is discussed. In addition, a new route to cyclopentenones via ruthenium-catalyzed carbonylative cyclization of allylic carbonates with alkenes, which would be the complement of the catalytic intermolecular Pauson-Khand reaction, is also presented.
Keywords: ruthenium catalysis, allylruthenium intermediates, chemoselective reactions, regioselective reactions, allylruthenium complexe, pauson-khand reaction
Current Organic Chemistry
Title: Advances in Ruthenium Catalysis. Novel Catalytic Reactions via η3- Allylruthenium Intermediates
Volume: 6 Issue: 13
Author(s): Teruyuki Kondo and Take-aki Mitsudo
Affiliation:
Keywords: ruthenium catalysis, allylruthenium intermediates, chemoselective reactions, regioselective reactions, allylruthenium complexe, pauson-khand reaction
Abstract: Recent developments in ruthenium-catalyzed chemo-, regio-, and stereoselective C-C bond forming reactions as well as a C-C bond cleaving reaction via an η3-allylruthenium intermediate are disclosed, in which novel ambiphilic reactivity of η3-allylruthenium complexes is discussed. In addition, a new route to cyclopentenones via ruthenium-catalyzed carbonylative cyclization of allylic carbonates with alkenes, which would be the complement of the catalytic intermolecular Pauson-Khand reaction, is also presented.
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Cite this article as:
Kondo Teruyuki and Mitsudo Take-aki, Advances in Ruthenium Catalysis. Novel Catalytic Reactions via η3- Allylruthenium Intermediates, Current Organic Chemistry 2002; 6 (13) . https://dx.doi.org/10.2174/1385272023373545
DOI https://dx.doi.org/10.2174/1385272023373545 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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