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Current Organic Chemistry
ISSN (Print): 1385-2728
ISSN (Online): 1875-5348
VOLUME: 6
ISSUE: 13
DOI: 10.2174/1385272023373545      Price:  $58









Advances in Ruthenium Catalysis. Novel Catalytic Reactions via η3- Allylruthenium Intermediates

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Author(s): Teruyuki Kondo and Take-aki Mitsudo
Pages 1163-1179 (17)
Abstract:
Recent developments in ruthenium-catalyzed chemo-, regio-, and stereoselective C-C bond forming reactions as well as a C-C bond cleaving reaction via an η3-allylruthenium intermediate are disclosed, in which novel ambiphilic reactivity of η3-allylruthenium complexes is discussed. In addition, a new route to cyclopentenones via ruthenium-catalyzed carbonylative cyclization of allylic carbonates with alkenes, which would be the complement of the catalytic intermolecular Pauson-Khand reaction, is also presented.
Keywords:
ruthenium catalysis, allylruthenium intermediates, chemoselective reactions, regioselective reactions, allylruthenium complexe, pauson-khand reaction
Affiliation:
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan