Metal Mediated and Catalyzed Nucleophilic Additions to Cyclopropenes

Author(s): Joseph M. Fox , Ni Yan .

Journal Name: Current Organic Chemistry

Volume 9 , Issue 7 , 2005

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Abstract:

This review describes the literature of nucleophilic additions of organometallic and metal hydride reagents to cyclopropenes with a particular focus on the regiochemical and stereochemical aspects of the addition reactions.

Keywords: walsh model, cyclopropene chemistry, carbometallation, electrophiles, alkylzinc addition, grignard reagents, cyclopropylbutyrolactones, natural products synthesis, hydroboration

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Article Details

VOLUME: 9
ISSUE: 7
Year: 2005
Page: [719 - 732]
Pages: 14
DOI: 10.2174/1385272053765006
Price: $58

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