Abstract
The chemistry of esters of hydrazonoic acids has gained increased interest in both synthetic organic chemistry and biological fields. Since a large number of developments in the use of such esters, a review of such developments, covering the literature up to mid 2005, seems to be of considerable value. The present review presents their structural features, nomenclature, synthetic methods and chemical reactions. The utility of the latter reactions for synthesis of various heterocyclic ring systems including mono-, bi-, tri-, tetra-, and penta-heterocycles. In addition, their silicon chelates and biological applications are presented.
Keywords: alkyl alkanehydrazonates, phosphotrihydrazides, cyclic hydrazonates, Transesterification, Aminolysis, Base-catalyzed Rearrangement, Grignard Reagents
Current Organic Chemistry
Title: The Chemistry of Hydrazonates
Volume: 11 Issue: 9
Author(s): Ahmad Sami Shawali and Sherif Mourad Sherif
Affiliation:
Keywords: alkyl alkanehydrazonates, phosphotrihydrazides, cyclic hydrazonates, Transesterification, Aminolysis, Base-catalyzed Rearrangement, Grignard Reagents
Abstract: The chemistry of esters of hydrazonoic acids has gained increased interest in both synthetic organic chemistry and biological fields. Since a large number of developments in the use of such esters, a review of such developments, covering the literature up to mid 2005, seems to be of considerable value. The present review presents their structural features, nomenclature, synthetic methods and chemical reactions. The utility of the latter reactions for synthesis of various heterocyclic ring systems including mono-, bi-, tri-, tetra-, and penta-heterocycles. In addition, their silicon chelates and biological applications are presented.
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Cite this article as:
Ahmad Sami Shawali and Sherif Mourad Sherif , The Chemistry of Hydrazonates, Current Organic Chemistry 2007; 11 (9) . https://dx.doi.org/10.2174/138527207780831747
DOI https://dx.doi.org/10.2174/138527207780831747 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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