Non Camphor Based Sultam Chiral Auxiliaries

Author(s): Albert W. M. Lee, W. H. Chan, Shu-Jia Zhang, Hong-Kui Zhang.

Journal Name: Current Organic Chemistry

Volume 11 , Issue 2 , 2007

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Abstract:

Sulfonamide is an important functional group. Its cyclic version, sultam, has been successfully employed as a chiral auxiliary in controlling diastereoselectivities of numerous organic transformations. In this paper, the uses of chiral sultams that are not derived from camphor as chiral auxiliaries in asymmetric syntheses are reviewed.

Keywords: camphorsultams, Benzosultams, cyclopentadiene, ring closing metathesis (RCM), cycloaddition reaction, diastereoselectivity

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Article Details

VOLUME: 11
ISSUE: 2
Year: 2007
Page: [213 - 228]
Pages: 16
DOI: 10.2174/138527207779316435
Price: $58

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