Abstract
N-Acylamidophosphinates RC(X)NHP(Y)R2 (NAAP) and their thioanalogues (X,Y= O, S; R = Alk, Ar, CCl3, Het, NR2 2, NR2R3; R = Ar, OAlk, OAr, SAlk, NAlk2, NHAr) contain X, Y donor atoms and amide nitrogen, which are capable of taking in complexation with metal cations. An application of NAAP complexes in supramolecular chemistry has been investigated in the last decades. Developed synthetic methods allow us to obtain N-acylamidophosphinate ligands contained multiple chelating groups or a combination of several essentially various coordinating fragments in the molecule: chelating moiety C(X)NHP(Y) and a macrocycle. The latter ligands are capable of connecting ions simultaneously by the chelating sites, and by the "guest-host" mechanism using the macrocycle. The bibliography includes 104 references.
Keywords: thiophosphoric acids, polyfunctional ligands, intramolecular hydrogen bonds, N-phosphorylated amides, coordination compounds, crown-containing ligands
Current Organic Chemistry
Title: N-Acylamidophosphinates: Structure, Properties and Complexation Towards Main Group Metal Cations
Volume: 10 Issue: 1
Author(s): F. D. Sokolov, V. V. Brusko, N. G. Zabirov and R. A. Cherkasov
Affiliation:
Keywords: thiophosphoric acids, polyfunctional ligands, intramolecular hydrogen bonds, N-phosphorylated amides, coordination compounds, crown-containing ligands
Abstract: N-Acylamidophosphinates RC(X)NHP(Y)R2 (NAAP) and their thioanalogues (X,Y= O, S; R = Alk, Ar, CCl3, Het, NR2 2, NR2R3; R = Ar, OAlk, OAr, SAlk, NAlk2, NHAr) contain X, Y donor atoms and amide nitrogen, which are capable of taking in complexation with metal cations. An application of NAAP complexes in supramolecular chemistry has been investigated in the last decades. Developed synthetic methods allow us to obtain N-acylamidophosphinate ligands contained multiple chelating groups or a combination of several essentially various coordinating fragments in the molecule: chelating moiety C(X)NHP(Y) and a macrocycle. The latter ligands are capable of connecting ions simultaneously by the chelating sites, and by the "guest-host" mechanism using the macrocycle. The bibliography includes 104 references.
Export Options
About this article
Cite this article as:
Sokolov D. F., Brusko V. V., Zabirov G. N. and Cherkasov A. R., N-Acylamidophosphinates: Structure, Properties and Complexation Towards Main Group Metal Cations, Current Organic Chemistry 2006; 10 (1) . https://dx.doi.org/10.2174/138527206775193031
DOI https://dx.doi.org/10.2174/138527206775193031 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
Call for Papers in Thematic Issues
Advances of Heterocyclic Chemistry with Pesticide Activity
Global food safety and security will continue to be a global concern for the next 50 years and beyond. Plant diseases have had a significant impact on food safety and security throughout the entire food chain, from primary production to consumption. While conventional chemical pesticides have been traditionally used for ...read more
Calculation design of covalent/metal organic framework based catalysts
This research area combines theoretical computation and screening with machine learning for the design of covalent/metal organic framework-based catalysts, bridging the disciplines of organic chemistry, physical chemistry, computational chemistry, materials science, and machine learning. It covers several critical aspects: designing and synthesizing organic catalysts for improved performance, applying computational methods ...read more
Carbohydrates conversion in biofuels and bioproducts
Biomass pretreatment, hydrolysis, and saccharification of carbohydrates, and sugars bioconversion in biofuels and bioproducts within a biorefinery framework. Carbohydrates derived from woody biomass, agricultural wastes, algae, sewage sludge, or any other lignocellulosic feedstock are included in this issue. Simulation, techno-economic analysis, and life cycle analysis of a biorefinery process are ...read more
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
Related Journals
- Author Guidelines
- Graphical Abstracts
- Fabricating and Stating False Information
- Research Misconduct
- Post Publication Discussions and Corrections
- Publishing Ethics and Rectitude
- Increase Visibility of Your Article
- Archiving Policies
- Peer Review Workflow
- Order Your Article Before Print
- Promote Your Article
- Manuscript Transfer Facility
- Editorial Policies
- Allegations from Whistleblowers
- Announcements
Related Articles
-
Recent Findings Regarding Pathogenesis and Prevention of Ventilator- Associated Pneumonia
Current Respiratory Medicine Reviews Ewing’s Sarcoma Cancer Stem Cell Targeted Therapy
Current Stem Cell Research & Therapy Lipid Mediator Profiling in Pulmonary Disease
Current Pharmaceutical Biotechnology A Viewpoint on Angiotensin-Converting Enzyme 2, Anti-Hypertensives and Coronavirus Disease 2019 (COVID-19)
Infectious Disorders - Drug Targets Honokiol: A Novel Natural Agent for Cancer Prevention and Therapy
Current Molecular Medicine Biomarkers For the Diagnosis of Depression: Recent Updates
Current Psychiatry Research and Reviews Neurologic Sequelae in Critical Illness: Evaluation and Outcomes
Current Respiratory Medicine Reviews Structural Alerts of Mutagens and Carcinogens
Current Computer-Aided Drug Design Redox Processes in Neurodegenerative Disease Involving Reactive Oxygen Species
Current Neuropharmacology Cell Therapy for Respiratory Diseases: Optimizing Cell Delivery Strategies
Current Respiratory Medicine Reviews A Composite Study of Coagulation Milieu in Covid-19: Experience from a Tertiary Care Centre from India
Cardiovascular & Hematological Disorders-Drug Targets Clinical Presentation, Outcome and Risk Factors of Late-Onset Non- Infectious Pulmonary Complications After Allogeneic Stem Cell Transplantation
Current Stem Cell Research & Therapy Repurposing Chloroquine Analogs as an Adjuvant Cancer Therapy
Recent Patents on Anti-Cancer Drug Discovery G-Protein Coupled Receptors (GPCRs): A Comprehensive Computational Perspective
Combinatorial Chemistry & High Throughput Screening Cross-Talk between Oxidative Stress and Pro-Inflammatory Cytokines in Acute Pancreatitis: A Key Role for Protein Phosphatases
Current Pharmaceutical Design Preface
Current Proteomics Detection of COVID-19 Incidentally in <sup>68</sup>Ga-PSMA PET/CT for Restaging of Prostate Cancer
Current Medical Imaging In-Silico Analysis of Chromone Containing Sulfonamide Derivatives as Human Carbonic Anhydrase Inhibitors
Medicinal Chemistry The Applications of Machine Learning Algorithms in the Modeling of Estrogen-Like Chemicals
Combinatorial Chemistry & High Throughput Screening New Derivatives of BM212: A Class of Antimycobacterial Compounds Based on the Pyrrole Ring as a Scaffold
Mini-Reviews in Medicinal Chemistry