Advances in Organic Synthesis

Volume: 1

Indexed in: Chemical Abstracts, EBSCO, Ulrich's Periodicals Directory

Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challenging structures. It presents comprehensive articles written by eminent authorities ...
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Supramolecular Catalysis of Organic Reactions Involving Cyclodextrins

Pp. 301-339 (39)

K. Rama Rao, Y. V.D. Nageswar, N. Srilakshmi Krishnaveni and K. Surendra

Abstract

Supramolecular catalysis by cyclodextrins involving non-covalent inter molecular forces and host-guest complexation has been shown to result in high selectivities in a variety of organic reactions by the cyclodextrin molecular recognition ability and effective use of their hydroxyl groups and derivatives. Some of the applications of cyclodextrins discussed are: enzyme models, enzyme catalysed reactions, regioselective ring opening reactions, photo chemical reactions, oxidations, enantioselective reactions etc. Recent developments in the modification of cyclodextrins to attain good geometric control for accelerating the reactions has been highlighted.

Affiliation:

Organic Chemistry Division-I, Indian Institute of Chemical Technology Hyderabad-500 007, India.