Advances in Organic Synthesis

Volume: 1

The volume focuses on recent advances in organofluorine chemistry directed towards selective fluorine introduction into various target molecules, employing both traditional and contemporary, ...
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Activation of Organic Reactions by Perchlorates

Pp. 215-232 (18)

Suvarna S. Deshpande and Anil Kumar

Abstract

Perchlorates have been frequently employed to promote a variety of synthetic transformations under ambient conditions. For example, the LiClO4-diethyl ether solvent medium has proven to be a powerful substitute for external high pressure for Diels-Alder reactions and other organic reactions. In this chapter are discussed several such organic transformations where perchlorates have played highly significant role in promoting their rates and yields.

Affiliation:

Physical Chemistry Division, National Chemical Laboratory, Pune 411008, India.