Recent Advances in Preparation and Application of Functionalized Mesoporous Materials

Author(s): Jianghong Liu*, Xiaohang Wei, Dandan Yuan, Jingwei Ren, Jian Xue.

Journal Name: Recent Innovations in Chemical Engineering
Formerly: Recent Patents on Chemical Engineering

Volume 12 , Issue 3 , 2019

Become EABM
Become Reviewer

Graphical Abstract:


Abstract:

Functionalized mesoporous materials are widely used in the environmental field due to their excellent adsorption and catalytic properties. The materials with different functions are obtained by modifying mesoporous materials. In this paper, the preparation methods of functional mesoporous materials with functional groups, metal doping and acid modified were presented. This review focused on the main features and applied prospects of functionalized mesoporous materials under three producing methods. Recent advances of functionalized mesoporous materials in the fields of adsorption and catalysis have been summarized. Adsorption mainly refers to the treatment of heavy metals, organic contaminant, dyestuff and CO2. Finally, the trends and application foreground of functionalized mesoporous materials were elaborated in this paper, which provided reference and guidance for the development of functional mesoporous materials.

Keywords: Modification, adsorption, heavy metal ions, metal-doped, mesoporous materials, catalysis.

[1]
Kresge CT, Leonowics ME, Both WJ, et al. Ordered mesoporous molecular sieves synthesized through a liquid- crystal template mechanism. J Nature 1992; 359(6397): 710-2.
[http://dx.doi.org/10.1038/359710a0]
[2]
Beck JS, Vartuli JC, Roth WJ, et al. A new family of mesoporous molecular sieves prepared with liquid crystal templates. J Am Chem Soc 1992; 114(27): 10834-43.
[http://dx.doi.org/10.1021/ja00053a020]
[3]
Bagshaw SA, Prouzet E, Pinnavaia TJ. Templating of mesoporous molecular sieves through nonionic polyethylene oxide surfactants. J Sci 1995; 269(5228): 1242-4.
[http://dx.doi.org/10.1126/science.269.5228.1242] [PMID: 17732109]
[4]
Kim SS, Zhang W, Pinnavaia TJ. Ultrastable mesostructured silica vesicles. J Sci 1998; 282(5392): 1302-5.
[http://dx.doi.org/10.1126/science.282.5392.1302] [PMID: 9812891]
[5]
Huo QS, Margolese DI, Ciesla U, et al. Organization of organic molecules with inorganic molecular species into nanocomposite biphase arrays. J Chem Mater 1994; 6(8): 1176-91.
[http://dx.doi.org/10.1021/cm00044a016]
[6]
Stucky GD, Huo Q. Directed synthesis of organic/inorganic composite structures. J Progress in Zeolite and Micropaous Materials 1997; 105(22): 3-28.
[http://dx.doi.org/10.1016/S0167-2991(97)80534-4]
[7]
Zhao D, Feng J, Huo Q, et al. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores. J Sci 1998; 279(5350): 548-52.
[http://dx.doi.org/10.1126/science.279.5350.548] [PMID: 9438845]
[8]
Zhao DY, Huo QS, Feng JL, et al. Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. J Am Chem Soc 1998; 120(24): 6024-36.
[http://dx.doi.org/10.1021/ja974025i]
[9]
Mark J, Kevin E, Wadood Y, et al. Chiral nematic mesoporous carbon EP2707327 2017.
[10]
Da’Na E. Adsorption of heavy metals on functionalized-mesoporous silica: A review. J Microporous Mesoporous Mater 2017; 2017(247): 145-57.
[http://dx.doi.org/10.1016/j.micromeso.2017.03.050]
[11]
He R, Wang Z, Tan L, et al. Design and fabrication of highly ordered ion imprinted SBA-15 and MCM-41 mesoporous organosilica for efficient removal of Ni+2 from different properties of wastewaters. J Microporous Mesoporous Mater 2018; 2017(257): 212-21.
[http://dx.doi.org/10.1016/j.micromeso.2017.08.007]
[12]
Liu S, Wei M, Zheng X, et al. Alizarin red S functionalized mesoporous silica modified glassy carbon electrode for electrochemical determination of anthracene. J Electrochim Acta 2015; 2015(160): 108-13.
[http://dx.doi.org/10.1016/j.electacta.2014.12.120]
[13]
Burkett SL, Sims SD, Mann SC. Synthesis of hybrid inorganic organic mesoporous silica through co-condensation of siloxane and organosiloxane precursors. J Chem Commun (Camb) 1996; 11(11): 1367-8.
[http://dx.doi.org/10.1039/CC9960001367]
[14]
Liu Y, Zhang D, Xue P, et al. Ultralight MgO and its efficient adsorption to Pb+2 and Mn+2. J Recent Innov Chem Eng 2017; 10(1): 18-26.
[http://dx.doi.org/10.2174/2405520410666170621100921]
[15]
Liu SM, Yu JK, Zong K, et al. Method for preparing phenyl functionalized radial magnetic core-shell mesoporous silicon material CN104069818A 2014.
[16]
Stein A, Melde BJ, Schroden RC. Hybrid inorganic-organic mesoporous silicates nanoscopic reactors coming of age. J Adv Mater 2010; 12(19): 1403-19.
[http://dx.doi.org/10.1002/1521-4095(200010)12:19 <1403:AID-ADMA1403>3.0.CO;2-X]
[17]
Jaroniec CP, Kruk M, Jaroniec M, et al. Tailoring surface and structural properties of MCM-41 silica through bonding organosilanes. J Phys Chem B 1998; 102(28): 5503-10.
[http://dx.doi.org/10.1021/jp981304z]
[18]
Wu H. Cobalt-based fischer-tropsch synthesis catalyst coated with mesoporous materials and preparation method therefor EP3135372 2018.
[19]
Lin Q, Zhang JQ, Guo ZP, et al. Method for preparing Fe3O4 at MCM41 magnetic composite material through sol-gel method CN107899540A 2018.
[20]
Kurttepeli M, Locus R, Verboekend D, et al. Synthesis of aluminum-containing hierarchical mesoporous materials with columnar mesopore ordering through evaporation induced self-assembly. J Microporous Mesoporous Mater 2016; 2016(234): 186-95.
[http://dx.doi.org/10.1016/j.micromeso.2016.07.002]
[21]
Berrichi ZE, Cherif L, Orsen O, et al. Ga doped SBA-15 as an active and stable catalyst for Friedel-Crafts liquid-phase acylation. J. Appl Catal A Gen 2006; 298(1): 194-202.
[http://dx.doi.org/10.1016/j.apcata.2005.10.005]
[22]
Kumaran GM, Garg S, Soni K, et al. Effect of Al-SBA-15 support on catalytic functionalities of hydrotreating catalysts: I. Effect of variation of Si/Al ratio on catalytic functionalities. J. Appl Catal A Gen 2006; 305(2): 123-9.
[http://dx.doi.org/10.1016/j.apcata.2006.02.057]
[23]
Du J, Xu H, Shen J, et al. Catalytic dehydrogenation and cracking of industrial dipentene over M/SBA-15 catalysts. J. Appl Catal A Gen 2005; 296(2): 186-93.
[http://dx.doi.org/10.1016/j.apcata.2005.08.030]
[24]
Liu YH, Li ZJ, Shen WZ. surface chemical functional groups modification of porous carbon. J Recent Pat Chem Eng 2008; 1(1): 10-5.
[25]
Tenorio MJ, Morère J, Carnerero C, et al. Thiol group functionalization of mesoporous SiO2 SBA-15 using supercritical CO2. J Microporous Mesoporous Mater 2017; 2017(256): 147-54.
[26]
Fayyad MK. Amino-and thiol-modified microporous silicalite-1 and mesoporous MCM-48 materials as potential effective adsorbents for Pb(II) in polluted aquatic systems. J Adsorpt Sci Technol 2017; 36(1): 270-86.
[27]
Hao S, Verlotta A, Aprea P, et al. Optimal synthesis of amino-functionalized mesoporous silica for the adsorption of heavy metal ions. J Microporous Mesoporous Mater 2016; 2016(236): 250-9.
[http://dx.doi.org/10.1016/j.micromeso.2016.09.008]
[28]
Ge S, He X, Zhao J, et al. Removal of cationic dyes, heavy metal ions, and CO2 capture through adsorption on mesoporous silica HMS. J Water Air Soil Pollut 2017; 228(12): 2-10.
[http://dx.doi.org/10.1007/s11270-017-3645-5]
[29]
Wang B, Zhou Y, Li L, et al. Preparation of amidoxime-functionalized mesoporous silica nanospheres (ami-MSN) from coal fly ash for the removal of U(VI). J Sci Total Environ 2018; 62(6): 219.
[30]
Barczak M, Dobrzyńska J, Oszust M, et al. Synthesis and application of thiolated mesoporous silica for sorption, preconcentration and determination of platinum. J Mater Chem Phys 2016; 181(42): 126-35.
[http://dx.doi.org/10.1016/j.matchemphys.2016.06.042]
[31]
Liu S, Chen J, Peng Y, et al. Studies on toluene adsorption performance and hydrophobic property in phenyl functionalized KIT-6. Chem Eng J 2018; 334(17): 191-7.
[http://dx.doi.org/10.1016/j.cej.2017.08.091]
[32]
Zhang Z, Li H, Liu H. Insight into the adsorption of tetracycline onto amino and amino-Fe3+ functionalized mesoporous silica: Effect of functionalized groups. J Environ Sci (China) 2018; 65(3): 171-8.
[http://dx.doi.org/10.1016/j.jes.2016.10.020] [PMID: 29548388]
[33]
Suriyanon N, Permrungruang J, Kaosaiphun J, Wongrueng A, Ngamcharussrivichai C, Punyapalakul P. Selective adsorption mechanisms of antilipidemic and non-steroidal anti-inflammatory drug residues on functionalized silica-based porous materials in a mixed solute. J Chemosphere 2015; 136(136): 222-31.
[http://dx.doi.org/10.1016/j.chemosphere.2015.05.005] [PMID: 26025186]
[34]
Gen YB, Liu YH, Zhao K. Application status and research progress of biological treatment technology of printing and dyeing wastewater. J Gongye Yongshui Yu Feishui 2010; 41(4): 1-4.
[35]
Iordache O, Cornea CP, Dumitrescu I. Decolorization of bemacid azo-dyes through Aspergillus niger. J Biotechnol 2015; 208(4): S57-7.
[http://dx.doi.org/10.1016/j.jbiotec.2015.06.169]
[36]
Ge S, Geng W, He X, et al. Effect of framework structure, pore size and surface modification on the adsorption performance of methylene blue and Cu2+ in mesoporous silica. J. Colloids Surf A Physicochem Eng Asp 2018; 2018(539): 154-62.
[http://dx.doi.org/10.1016/j.colsurfa.2017.12.016]
[37]
Qin Q, Ma J, Liu K. Adsorption of anionic dyes on ammonium-functionalized MCM-41. J Hazard Mater 2009; 162(1): 133-9.
[http://dx.doi.org/10.1016/j.jhazmat.2008.05.016] [PMID: 18571846]
[38]
Yan X, Zhang L, Zhang Y, et al. Amine-modified SBA-15: Effect of pore structure on the performance for CO2 capture. J Ind Eng Chem Res 2011; 50(6): 3220-6.
[http://dx.doi.org/10.1021/ie101240d]
[39]
Wei J, Shi J, Pan H, et al. Adsorption of carbon dioxide on organically functionalized SBA-16. J Microporous Mesoporous Mater 2008; 116(1): 394-9.
[http://dx.doi.org/10.1016/j.micromeso.2008.04.028]
[40]
Belmabkhout Y, Serna-Guerrero R, Sayari A. Adsorption of CO2-containing gas mixtures over amine-bearing pore-expanded MCM-41 silica: Application for CO2 separation. J Adsorption 2011; 17(2): 395-401.
[http://dx.doi.org/10.1007/s10450-011-9348-0]
[41]
Wiesner UB, Werner JG. Gyroidal mesoporous carbon materials and methods there of US. Angew Chem Int Ed Engl 2008; 47(20): 3696-717.
[42]
Gao F, Zhang Y, Wan H, et al. The states of vanadium species in V-SBA-15 synthesized under different pH values. J Microporous Mesoporous Mater 2008; 110(2): 508-16.
[http://dx.doi.org/10.1016/j.micromeso.2007.06.041]
[43]
Yang G, Chen X, Wang X, et al. Nickel(II) complex anchored on MCM-41 for the epoxidation of styrene through oxygen. J Chin J Catal 2013; 34(7): 1326-32.
[http://dx.doi.org/10.1016/S1872-2067(12)60568-3]
[44]
Fu Y, Gao S, Xiong C, et al. Direct templating assembly route for preparation of highly-dispersed vanadia species encapsulated in mesoporous MCM-41 channel. J RSC Advances 2015; 5(88): 72099-106.
[http://dx.doi.org/10.1039/C5RA12363A]
[45]
Cui H, Zhang Y, Zhao L, et al. Adsorption synthesized cobalt-containing mesoporous silica SBA-15 as highly active catalysts for epoxidation of styrene with molecular oxygen. J Catal Commun 2011; 12(6): 417-20.
[http://dx.doi.org/10.1016/j.catcom.2010.11.009]
[46]
Kong Y, Xinjie XU, Yong WU, et al. Effect of promoters on the catalytic activity of MCM-41 with high copper content in benzene hydroxylation. Chin J Catal 2008; 29(4): 385-90.
[http://dx.doi.org/10.1016/S1872-2067(08)60035-2]
[47]
Samran B, Aungkutranont S, White TJ, et al. Room temperature synthesis of Ti-SBA-15 from silatrane and titanium-glycolate and its catalytic performance towards styrene epoxidation. J Sol-Gel Sci Technol 2011; 57(2): 221-8.
[http://dx.doi.org/10.1007/s10971-010-2345-z]


Rights & PermissionsPrintExport Cite as

Article Details

VOLUME: 12
ISSUE: 3
Year: 2019
Page: [239 - 247]
Pages: 9
DOI: 10.2174/2405520412666190705125639
Price: $65

Article Metrics

PDF: 12
HTML: 2