Light-matter Interaction Under Intense Field Conditions: Nonlinear Optical Properties of Metallic-dielectric Nanostructures

Author(s): Enza Fazio* , Luisa D'Urso , Rosalba Saija , Saveria Santangelo* , Fortunato Neri .

Journal Name: Current Nanomaterials

Volume 4 , Issue 1 , 2019

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Abstract:

Background: Metallic–dielectric plasmonic nanoparticles have recently aroused great interest in view of many and novel technological applications, based on the interaction between light and matter under intense field conditions, in nonlinear integrated photonics and opto-fluidics, thanks to the possibility of tuning their electronic and optical properties through a fine control of the synthesis parameters and their nanoparticles under a high-power laser, like the one used during z-scan measures.

Objective: The goal of this work is the study of nonlinear optical properties (as nonlinear refraction, scattering, two-photon absorption, optical limiting) of colloids synthesized in different liquid media by Pulsed laser ablation in liquids (PLAL), which is a photo-assisted synthesis technique ensuring the formation of stable, contaminant-free colloids directly during the ablation process.

Methods: Noble metal nanoparticles, metal oxides hybrid nanostructures and silicon-based nanomaterials, were prepared by nanosecond and picosecond PLAL technique, in different media. The third-order nonlinear optical (NLO) properties have been studied by the use of a single beam z-scan technique with Q-switched frequency doubled Nd:YAG laser (λ=532 nm) at 5 ns pulse.

Results: 1) A good stability of the PLAL nanocolloids under a high laser power; 2) the limiting threshold reduction inducted by the Ag-Au nanoparticles, the increase of the NLO absorption coefficient β, the reduction of the transmittance/scattering signal and the presence of a pronounced asymmetry of the peak/valley profile of the metal decorated metal oxide nanomaterials compared to the separately produced components.

Conclusion: An intriguing coupling between the nature of the optical limiting response and the nanostructures rearrangement upon intense field conditions, explaining z-scan data by a classical approach able to account for the nanoparticles asymmetry and plasmonic effects, are the main results found.

Keywords: Nonlinear optics, optical limiting, z-scan method, metal nanoparticles, metal-oxide nanostructures, pulsed laser ablation in liquids, T-matrix approach, torque force.

[1]
Marder SR, Sohn JE, Stucky GD. Materials for nonlinear optics chemical perspectives. American Chemical Society: Washington, DC 1991.
[2]
Schroer CG, Lengeler B. Handbook of Lasers and Optics. Springer-Verlag: New York 2007.
[3]
Ghosh S, Bhagwat AR, Renshaw CK, et al. Low-light-level optical interactions with rubidium vapor in a photonic band-gap fiber. Phys Rev Lett 2006; 97(2): 023603.
[4]
Tang SKY, Stan CA, Whitesides GM. Dynamically reconfigurable liquid-core liquid-cladding lens o in a microfluidic channel. Opt Express 2011; 19: 2204-15.
[5]
Song C, Nguyen NT, Asundi AK, Low CLN. Biconcave micro-optofluidic lens with low-refractive-index liquids. Opt Lett 2009; 34(23): 3622-4.
[6]
Hashimoto M, Mayers B, Garstecki P, Whitesides GM. Flowing lattices of bubbles as tunable, self-assembled diffraction gratings. Small 2006; 2(11): 1292-8.
[7]
Lapsley MI, Lin SC, Mao X, Huang TJ. An in-plane, variable optical attenuator using a fluid-based tunable reflective interface. Appl Phys Lett 2009; 95(8): 083507.
[8]
Xiao G, Zhu Q, Shen Y, et al. A tunable submicro-optofluidic polymer filter based on guided-mode resonance. Nanoscale 2015; 7(8): 3429-34.
[9]
Chao KS, Lin MS, Yang RJ. An in-plane optofluidic microchip for focal point control. Lab Chip 2013; 13(19): 3886-92.
[10]
Rashidian M, Dorranian D. Investigation of optical limiting in nanometal. Rev Adv Mater Sci 2015; 40: 110-26.
[11]
Fazio E, Neri F, Patanè S, D’Urso L, Compagnini G. Optical limiting effects in linear carbon chains. Carbon 2011; 49: 306-10.
[12]
Fazio E, Barreca F, Spadaro S, Currò G, Neri F. Preparation of luminescent and optical limiting silicon nanostructures by nanosecond-pulsed laser ablation in liquids. Mater Chem Phys 2011; 130: 418-24.
[13]
Fazio E, Calandra P, Liveri VVT, Santo N, Trusso S. Synthesis and physico-chemical characterization of Au/TiO2 nanostructures formed by “cold” and “hot” nanosoldering of Au and TiO2 nanoparticles dispersed in water. Colloids Surf A Physicochem Eng Asp 2011; 392: 171-7.
[14]
Messina E, D’Urso L, Fazio E, et al. Tuning the structural and optical properties of gold/silver nano-alloys prepared by laser ablation in liquids for optical limiting, ultra-sensitive spectroscopy, and optical trapping. J Quant Spectrosc Radiat Transf 2012; 113(18): 2490-8.
[15]
Forte G, D’Urso L, Fazio E, et al. The effects of liquid environments on the optical properties of linear carbon chains prepared by laser ablation generated plasmas. Appl Surf Sci 2013; 272: 76-81.
[16]
Fazio E, Neri F. Nonlinear optical effects from Au nanoparticles prepared by laser plasmas in water. Appl Surf Sci 2013; 272: 88-93.
[17]
Fazio E, D’Urso L, Consiglio G, et al. Nonlinear scattering and absorption phenomena in size-selected diphenylpolyynes. J Phys Chem C 2014; 118: 28812-9.
[18]
Fazio E, D’Urso L, Santangelo S, Saija R, Compagnini G, Neri F. The activation of non-linear optical response in Ag@ZnO nanocolloids under an external highly intense electric field. Il Nuovo Cimento 2016; 39(3): 16.
[19]
Sagor RH, Ghulam Saber G, Alsunaidi MA. Numerical study of propagation properties of surface plasmon polaritons in nonlinear media. Eur Phys J D 2016; 70: 65.
[20]
Fazio E, Santoro M, Lentini G, Franco D, Guglielmino SPP, Neri F. Iron oxide nanoparticles prepared by laser ablation: synthesis, structural properties and antimicrobial activity. Colloids Surf A Physicochem Eng Asp 2016; 490: 98-103.
[21]
D’Urso L, Santangelo S, Spadaro S, et al. Enhanced optical response of ZnO nanocolloids prepared by a picosecond laser source. J Lumin 2016; 178: 204-9.
[22]
Leonardi SG, Santoro M, Neri G, Neri F. Synthesis, characterization and hydrogen sensing properties of nanosized colloidal rhodium oxides prepared by Pulsed Laser Ablation in water. Sens Actuators B Chem 2018; 262: 79-85.
[23]
Fazio E, Spadaro S, Bonsignore M, et al. Molibdenum oxide nanoparticles for the sensitive detection of dopamine. J Electroanal Chem 2018; 814: 91-6.
[24]
Fazio E, Speciale A, Spadaro S, et al. Evaluation of biological response induced by molybdenum oxide nanocolloids on in vitro cultured NIH/3T3 fibroblast cells by micro-Raman spectroscopy. Colloids Surf B Biointerfaces 2018; 170: 233-41.
[25]
Fazio E, Neri F, Savasta S, Spadaro S, Trusso S. Surface-enhanced Raman scattering of SnO2 bulk material and colloidal solutions. Phys Rev B Condens Matter Mater Phys 2012; p. 85195423.
[26]
Fazio E, Patanè S, Scibilia S, et al. Structural and optical properties of pulsed laser deposited ZnO thin films. Curr Appl Phys 2013; 13: 710-6.
[27]
Fazio E, Cacciola A, Mezzasalma AM, Mondio G, Neri F, Saija R. Modelling of the optical absorption spectra of PLAL prepared ZnO colloids. J Quant Spectrosc Radiat Transf 2013; 124: 86-93.
[28]
Akhmanov SA, Sukhorukov AP, Khokhlov RV. Self-focusing ad diffraction of light in anonlinear medium. Sov Phys Usp 1968; 10: 5.
[29]
Panoiu NC, Sha WEI, Lei DY, Li G-C. Nonlinear optics in plasmonic nanostructures. J Opt 2018; 20(8): 083001.
[30]
Valligatla S, Haldar KK, Patra A, Desai NR. Nonlinear optical switching and optical limiting in colloidal CdSe quantum dots investigated by nanosecond Z-scan measurement. Opt Laser Technol 2016; 84: 87-93.
[31]
Tutt LW, Boggess TF. Review of optical limiting mechanisms and devices using organics, fullerenes, semiconductors and other materials. Prog Quantum Electron 1993; 17(4): 299-338.
[32]
Zhang YX, Wang YH. Nonlinear optical properties of metal nanoparticles: a review. RSC Advances 2017; 7: 45129-44.
[33]
Qu B, Ouyang Q, Yu X, Luo W, Qi L, Chen Y. Nonlinear absorption, nonlinear scattering, and optical limiting properties of MoS2-ZnO composite-based organic glasses. Phys Chem Chem Phys 2015; 17(8): 6036-43.
[34]
Dong N, Li Y, Feng Y, et al. Optical limiting and theoretical modelling of layered transition metal dichalcogenide nanosheets. Sci Rep 2015; 5: 14646-51.
[35]
Sheik-Bahae M, Said AA, Van Stryland EW. High-sensitivity, single-beam n(2) measurements. Opt Lett 1989; 14(17): 955-7.
[36]
Santoro M, Fazio E, Trusso S, et al. SERS sensing of Perampanel with nanostructured arrays of gold particles produced by pulsed laser ablation in liquid. Med Dev and Sens 2018; 1(1): 10003.
[37]
Qureshi FM, Martin SJ, Long X, et al. Optical limiting properties of a zinc porphyrin polymer and its dimer and monomer model compounds. Chem Phys 1998; 231: 87-94.
[38]
Daldosso N, Pavesi L. Nanosilicon. Elsevier: New York 2005.
[39]
Trusso S, Vasi C, Allegrini M, Fuso F, Pennelli G. Micro-Raman study of free-standing porous silicon samples. J Vac Sci Technol 1999; 17(2): 468-73.
[40]
Sharon SM, Chaure S, Doyle J, Colli A, Ferrari AC, Blau WJ. Scattering induced optical limiting in Si/SiO2 nanostructure dispersion. Opt Commun 2007; 276: 305-9.
[41]
Fuke N, Fukui A, Islam A, et al. Influence of TiO2/electrode interface on electron transport properties in back contact dye-sensitized solar cells. Sol Energy Mater Sol Cells 2009; 93: 720-4.
[42]
Wang Y, Ou JZ, Chrimes AF, et al. Plasmon resonances of highly doped two-dimensional MoS2. Nano Lett 2015; 15(2): 883-90.
[43]
Ghosh A, Choudhary RNP. Optical emission and absorption spectra of Zn–ZnO core-shell nanostructures. J Exp Nanosci 2010; 5(2): 134-42.
[44]
Zhang BY, Zavabeti A, Chrimes AF, et al. Degenerately hydrogen doped molybdenum oxide nanodisks for ultrasensitive plasmonic biosensing 2018; 28(11): 1706006.
[45]
Weber N, Protte M, Walter F, Georgi P, Zentgraf T, Meier C. Double resonant plasmonic nanoantennas for efficient second harmonic generation in zinc oxide. Phys Rev B 2017; 95(20): 95205307.
[46]
Jackson JD. Classical Electrodynamics. Wiley, New York 1975; pp. 456-506.


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Article Details

VOLUME: 4
ISSUE: 1
Year: 2019
Page: [51 - 62]
Pages: 12
DOI: 10.2174/2405461504666190510130720

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