Physical and Dielectric Properties of MnFe2O4 Doped by Mo

Author(s): F. Al-Mokdad* , R. Sayed Hassan , R. Awad .

Journal Name: Current Nanomaterials

Volume 4 , Issue 2 , 2019

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Abstract:

Background: The properties of spinel ferrites are known to be dependent on many various factors and mainly on the cations distribution among the tetrahedral and octahedral sites. Therefore, they are sensitive to the presence of doping cations, the type and the amount of these cations. Many researchers have focused on investigating the effect of doping on spinel ferrites nanoparticles with various types of dopants. Among the dopants, transition metal (TM) ions have shown significant effects and changes on the structural, optical, electric and magnetic properties of spinel ferrites nanoparticles.

Objectives: The goal of this work is to investigate the effect of the TM ions Mo5+ on the several properties of manganese ferrites nanoparticles.

Methods: Mo-doped manganese ferrites nanoparticles with the general formula MnFe2-xMoxO4 (0≤x≤ 0.1) were prepared by co-precipitation technique using two different methods, depending on the molarity of NaOH and the annealing temperatures. The characterization of the prepared samples was conducted by X-ray powder diffraction (XRD), Energy-Dispersive X-ray (EDX), Transmission Electron Microscopy (TEM), ultraviolet-visible (UV-Vis) absorption spectroscopy and Fourier Transform Infrared (FTIR) spectroscopy in order to investigate the effect of Mo-doping on the structure, crystallite size, morphology, energy gap and functional groups of MnFe2O4 nanoparticles. Vibrating sample magnetometer (VSM) was used to study the magnetic hysteresis of the samples.

Results: The XRD patterns show the segregation of MnFe2O4 phase into α-Fe2O3 and Mn2O3 for samples prepared at 4 M NaOH and annealing temperature of 873 K. Whereas, samples prepared at 2 M NaOH without annealing process, obtained a single phase of MnFe2O4. The Eg of both samples decreases with the increase in Mo-doping. FTIR confirms the presence of Fe-O bands corresponding to α-Fe2O3 for annealed samples, and the metal-O bands corresponding to octahedral and tetrahedral sites in non-annealed samples. Magnetic measurements show that annealed samples are antiferromagnetic whereas ferromagnetic behavior is observed in non-annealed samples. Dielectric measurements, for both samples, indicate that the dielectric parameters are strongly dependent on both Mo-concentrations and temperatures.

Conclusion: In order to get a single phase of MnFe2O4 nanoparticles, thermal treatment at high temperature and high molarity of NaOH are not recommended. Mo-doping has significant influences on the optical, magnetic and dielectric properties and therefore future studies on the Mo-doping with different and new doping percentages are recommended.

Keywords: MnFe2-xMoxO4 nanoparticles, FTIR, VSM, dielectric measurements, magnetic measurements, energy-dispersive X-ray.

[1]
Bucko MM, Haberko K. Hydrothermal synthesis of nickel ferrite powders, their properties and sintering. J Eur Ceram Soc 2007; 27: 723-7.
[2]
Shahane GS, Kumar A, Arora M, Pant RP, Lal K. Synthesis and characterization of Ni–Zn ferrite nanoparticles. J Magn Magn Mater 2010; 322: 1015-9.
[3]
Catalan G, Scott JF. Physics and applications of bismuth ferrite. Adv Mater 2009; 21(24): 2463-85.
[4]
Rana S, Gallo A, Srivastava RS, Misra RDK. On the suitability of nanocrystalline ferrites as a magnetic carrier for drug delivery: functionalization, conjugation and drug release kinetics. Acta Biomater 2007; 3(2): 233-42.
[5]
Lu J, Ma S, Sun J, et al. Manganese ferrite nanoparticle micellar nanocomposites as MRI contrast agent for liver imaging. Biomater 2009; 30(15): 2919-28.
[6]
Yan Y, Luo Y, Ma J, Li B, Xue H, Pang H. Facile synthesis of vanadium metal‐organic frameworks for high‐performance supercapacitors. Small 2018; 14(33)1801815
[7]
Yan Y, Li B, Guo W, Pang H, Xue H. Vanadium based materials as electrode materials for high performance supercapacitors. J Power Sources 2016; 329: 148-69.
[8]
Yan Y, Gu P, Zheng S, Zheng M, Pang H, Xue H. Facile synthesis of an accordion-like Ni-MOF superstructure for high-performance flexible supercapacitors. J Mater Chem A 2016; 4(48): 19078-85.
[9]
Dai Q, Patel K, Donatelli G, Ren S. Magnetic cobalt ferrite nanocrystals for an energy storage concentration cell. Angewandte Chemie 2016; 128(35): 10595-9.
[10]
Khan MA, Islam MU, Ishaque M, Rahman IZ. Magnetic and dielectric behavior of terbium substituted Mg1-xTbxFe2O4 ferrites. J Alloys Compd 2012; 519: 156.
[11]
Lungu A, Malaescu I, Marin CN, Vlazan P, Sfirloaga P. The electrical properties of manganese ferrite powders prepared by two different methods. Physica B 2015; 462: 80-5.
[12]
Aslibeiki B, Kameli P, Salamati H, Eshraghi M, Tahmasebi T. Superspin glass state in MnFe2O4 nanoparticles. J Magn Magn Mater 2010; 322: 2929-34.
[13]
Li J, Yuan H, Li G, Liu Y, Leng J. Cation distribution dependence of magnetic properties of sol–gel prepared MnFe2O4 spinel ferrite nanoparticles. J Magn Mater 2010; 322: 3396-400.
[14]
Komarneni S, D’Arrigo MC, Leonelli C, Pellacani GC, Katsuki H. Microwave‐hydrothermal synthesis of nanophase ferrites. J Am Ceram Soc 1998; 81(11): 3041-5.
[15]
Palamaru MN, Iordan AR, Aruxandei CD, et al. The synthesis of doped manganese cobalt ferrites by autocombustion technique. J Optoelectron Adv Mater 2008; 10(7): 1853-6.
[16]
Naseri MG, Saion EB, Ahangar HA, Hashim M, Shaari AH. Synthesis and characterization of manganese ferrite nanoparticles by thermal treatment method. J Magn Magn Mater 2011; 323(13): 1745-9.
[17]
Raghavender AT, Hong NH. Dependence of Néel temperature on the particle size of MnFe2O4. J Magn Magn Mater 2011; 323: 2145-7.
[18]
Mostafa NY, Hessien MM, Shaltout AA. Hydrothermal synthesis and characterizations of Ti substituted Mn-ferrites. J Alloys Compd 2012; 529: 29-33.
[19]
Malaescu I, Lungu A, Marin CN, Vlazan P, Sfirloaga P, Turi GM. Experimental investigations of the structural transformations induced by the heat treatment in manganese ferrite synthesized by ultrasonic assisted co-precipitation method. Ceram Int 2016; 42: 16744-8.
[20]
Heiba ZK, Mostafa NY, Abd-Elkader OH. Structural and magnetic properties correlated with cation distribution of Mo-substituted cobalt ferrite nanoparticles. J Magn Magn Mater 2014; 368: 246-51.
[21]
Heiba ZK, Mohamed MB, Wahba AM. Effect of Mo substitution on structural and magnetic properties of Zinc ferrite nanoparticles. J Mol Struct 2016; 1108: 347-51.
[22]
Lutterotti L, Matthies S, Wenk HR. MAUD (material analysis using diffraction): a user friendly Java program for Rietveld texture analysis and more. Twelfth international conference on textures of materials (ICOTOM-12). NRC Research Press Ottowa, Canada. 1999.
[23]
Teja AS, Koh PY. Synthesis, properties, and applications of magnetic iron oxide nanoparticles. Prog Cryst Growth 2009; 55: 22-45.
[24]
Siregar N, Indrayana IPT, Suharyadi E, Kato T, Iwata S. Effect of synthesis temperature and naoh concentration on microstructural and magnetic properties of Mn0.5Zn0.5Fe2O4 nanoparticles. IOP Conf Ser Mater Sci Eng. 2017; 202: 012048
[25]
Zhen L, He K, Xu CY, Shao WZ. Synthesis and characterization of single-crystalline MnFe2O4 nanorods via a surfactant-free hydrothermal route. J Magn Magn Mater 2008; 320: 2672-5.
[26]
Ansari MMN, Khan S. Structural, electrical and optical properties of sol-gel synthesized cobalt substituted MnFe2O4 nanoparticles. Physica B 2017; 520: 21-7.
[27]
Akl AA, Mahmoud SA, Al-Shomar SM, Hassanien AS. Improving microstructural properties and minimizing crystal imperfections of nanocrystalline Cu 2 O thin films of different solution molarities for solar cell applications. Mater Sci Semicond Process 2018; 74: 183-92.
[28]
Mustafa G, Islam MU, Zhang W, et al. Investigation of structural and magnetic properties of Ce3+-substituted nanosized Co–Cr ferrites for a variety of applications. J All Compd 2015; 618: 428-36.
[29]
Singh J, Singh C, Kaur D, Narang SB, Jotania R, Joshi R. Investigation on structural and microwave absorption property of Co2+ and Y3+ substituted M-type Ba-Sr hexagonal ferrites prepared by a ceramic method. J All Comp 2017; 695: 792-8.
[30]
Ali I, Shaheen N, Islam MU, et al. Study of electrical and dielectric behavior of Tb+3 substituted Y-type hexagonal ferrite. J All Comp 2014; 617: 863-8.
[31]
Mazen SA, Abu-Elsaad NI. Structural and some magnetic properties of manganese-substituted lithium ferrites. J Magn Magn Mater 2012; 324: 3366-73.
[32]
Kumbhar SS, Mahadik MA, Mohite VS, et al. Structural, dielectric and magnetic properties of Ni substituted zinc ferrite. J Magn Magn Mater 2014; 363: 114-20.
[33]
Joshi S, Kamble VB, Kumar M, Umarji AM, Srivastava G. Nickel substitution induced effects on gas sensing properties of cobalt ferrite nanoparticles. J Alloys Compd 2016; 654: 460-6.
[34]
Viswanathan B, VRK. Murthy, Eds. Ferrite materials: science and technology. Springer Verlag 1990.
[35]
Najjar R, Abdel-Gaber AM, Awad R. (2018). Electrochemical corrosion behaviour of carbon steel in acidic media in presence of mn2o3 nanoparticles synthesized at different pH. Int J Electrochem Sci 2018; 13: 8724.
[36]
Díaz C, Valenzuela ML, Laguna-Bercero MA, et al. Synthesis and magnetic properties of nanostructured metallic Co, Mn and Ni oxide materials obtained from solid-state metal-macromolecular complex precursors. RSC Advances 2017; 7(44): 27729-36.
[37]
Lassoued A, Lassoued MS, Dkhil B, Gadri A, Ammar S. Structural, optical and morphological characterization of Cu-doped α-Fe2O3 nanoparticles synthesized through co-precipitation technique. J Mol Struct 2017; 1148: 276-81.
[38]
Lassoued A, Dkhil B, Gadri A, Ammar S. Control of the shape and size of iron oxide (α-Fe2O3) nanoparticles synthesized through the chemical precipitation method. Results in physics 2017; 7: 3007-15.
[39]
Pan H, Meng X, Cai J, Li S, Qin G. 4d transition-metal doped hematite for enhancing photoelectrochemical activity: theoretical prediction and experimental confirmation. RCS Adv 2015; 5: 19353-61.
[40]
Gao G, Huang P, Zhang Y, Wang K, Qin W, Cui D. Gram scale synthesis of superparamagnetic Fe3O4 nanoparticles and fluid via a facile solvothermal route. CrystEngComm 2011; 13: 1782.
[41]
Naseri MG, Saion EB, Ahangar HA, Shaari AH, Hashim M. Simple synthesis and characterization of cobalt ferrite nanoparticles by a thermal treatment method. J Nanomater 2010; 2010: 75.
[42]
Sivakumar P, Ramesh R, Ramanand A, Ponnusamy S, Muthamizhchelvan C. Synthesis and characterization of nickel ferrite magnetic nanoparticles. Mater Res Bull 2011; 46: 2208-11.
[43]
Diaz-Guerra C, Pérez L, Piqueras J, Chioncel MF. Magnetic transitions in α- Fe2O3 nanowires. J Appl Phys 2009; 106(10)104302
[44]
Freyria FS, Barrera G, Tiberto P, et al. Eu-doped α-Fe2O3 nanoparticles with modified magnetic properties. J Solid State Chem 2013; 201: 302-11.
[45]
Wan H, Rong P, Liu X, et al. Morphological evolution and magnetic property of rare‐earth‐doped hematite nanoparticles: promising contrast agents for t1‐weighted magnetic resonance imaging. Adv Funct Mater 2017; 271606821
[46]
Zubair A, Ahmad Z, Mahmood A, et al. Structural, morphological and magnetic properties of Eu-doped CoFe2O4 nano-ferrites. Results Phys 2017; 7: 3203-8.
[47]
Khaleghi M, Moradmard H, Shayesteh SF. Cation distributions and magnetic properties of cu-doped nanosized mnfe2o4 synthesized by the coprecipitation method. IEEE Trans Magn 2018; 54(1): 1-5.
[48]
Hankare PP, Patil RP, Sankpal UB, et al. Magnetic and dielectric properties of nanophase manganese-substituted lithium ferrite. J Magn Magn Mater 2009; 321(19): 3270-3.
[49]
Shitre AR, Kawade VB, Bichile GK, Jadhav KM. X-ray diffraction and dielectric study of Co1−xCdxFe2−xCrxO4 ferrite system. Mater Lett 2002; 56(3): 188-93.
[50]
Koops CG. On the dispersion of resistivity and dielectric constant of some semiconductors at audiofrequencies. Phys Rev 1951; 83: 127.
[51]
Khan A, Bhuiyan MA, Al-Quaderi GD, et al. Dielectric and transport properties of Zn-substituted cobalt ferrites. J Bang Acad Sci 2013; 37: 73-82.
[52]
Rahman SA. Temperature, frequency and composition dependence of dielectric properties of Nb substituted Li-ferrites. Egypt J Solids 2006; 29: 131-40.
[53]
Hankare PP, Sankpal UB, Patil RP, Jadhav AV, Garadkar KM, Chougule BK. Magnetic and dielectric studies of nanocrystalline zinc substituted Cu–Mn ferrites. J Magn Magn Mater 2011; 323: 389-93.
[54]
Velhal NB, Patil ND, Shelke AR, Deshpande NG, Puri VR. Structural, dielectric and magnetic properties of nickel substituted cobalt ferrite nanoparticles: effect of nickel concentration. AIP Adv 2015; 5097166
[55]
Hench ll, West JK. Principles of Electronic Ceramics. Wiley, New York . 1990; 189
[56]
Singh AK, Goel TC, Mendiratta RG, Thakur OP, Prakash C. Dielectric properties of Mn-substituted Ni–Zn ferrites. J Appl Phys 2002; 91: 6626-9.


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Article Details

VOLUME: 4
ISSUE: 2
Year: 2019
Page: [125 - 136]
Pages: 12
DOI: 10.2174/2405461504666190405153730

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