Carbon-Carbon Bond Formation Facilitated by π-Complexed Organometallic Auxiliaries: An Overview

Author(s): Animesh Roy , Bilal A. Bhat , Salvatore D. Lepore* .

Journal Name: Letters in Organic Chemistry

Volume 16 , Issue 9 , 2019

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Abstract:

Organometallic moieties attached to substrates via π-complexation play an important role as auxiliaries. As described in the present review, η-linked auxiliaries have been employed to overcome numerous synthesis obstacles that continue to present significant challenges for catalyzed reactions. This has been particularly true in carbon-carbon bond forming reactions involving highly unsaturated systems such as arenes, dienes and allenes, which are emphasized here.

Keywords: Organometallic, auxiliaries, chromium tricarbonyl, arenes, dienes, allenes.

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Article Details

VOLUME: 16
ISSUE: 9
Year: 2019
Page: [689 - 696]
Pages: 8
DOI: 10.2174/1570178616666181203141515
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