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Letters in Organic Chemistry

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ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

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Review Article

Carbon-Carbon Bond Formation Facilitated by π-Complexed Organometallic Auxiliaries: An Overview

Author(s): Animesh Roy, Bilal A. Bhat and Salvatore D. Lepore*

Volume 16, Issue 9, 2019

Page: [689 - 696] Pages: 8

DOI: 10.2174/1570178616666181203141515

Price: $65

Abstract

Organometallic moieties attached to substrates via π-complexation play an important role as auxiliaries. As described in the present review, η-linked auxiliaries have been employed to overcome numerous synthesis obstacles that continue to present significant challenges for catalyzed reactions. This has been particularly true in carbon-carbon bond forming reactions involving highly unsaturated systems such as arenes, dienes and allenes, which are emphasized here.

Keywords: Organometallic, auxiliaries, chromium tricarbonyl, arenes, dienes, allenes.

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