Research Progress on Cross-coupling Reactions of Alkenylaluminum with Electrophilic Reagents

Author(s): Qing Han Li*, Xue Bei Shao, Yong Ding, Chang Wen, Zhi Gang Zhao.

Journal Name: Current Organic Chemistry

Volume 22 , Issue 15 , 2018

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Abstract:

Alkenylaluminum reagents are good nucleophiles for organic reactions because of their high reactivities, the high Lewis acidity of the aluminum center, and their low toxicities. Therefore, alkenylaluminum reagents are widely applied in many of organic reactions. This review summarizes the recent advance of the alkenylaluminum reagents applied in cross-coupling reactions, involving various reaction systems, properties of reaction and synthetic application.

Keywords: Alkenylaluminum reagents, Cross-coupling reaction, C-C bond formation, C-N bond formation, research progress, nucleophiles.

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Article Details

VOLUME: 22
ISSUE: 15
Year: 2018
Page: [1523 - 1535]
Pages: 13
DOI: 10.2174/1385272822666180704143509
Price: $58

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