Zeolite-encapsulated Mn(II) Complex: A New Nano Catalyst for the Synthesis of Modafinil and Its Derivatives

Author(s): Mohammad Javad Taghizadeh*, Huoman Karimi, Akbar Mirzaie.

Journal Name: Letters in Organic Chemistry

Volume 16 , Issue 7 , 2019

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Abstract:

The Mn-hydrazone Schiff base encapsulated into NaY has been prepared and characterized as a new heterogeneous catalyst. Elemental analysis, UV-Vis, infrared spectroscopic analysis, diffused reflectance spectroscopy, thermal analysis, small angle X-ray diffraction, and N2 sorption demonstrate the existence of Mn-hydrazone schiff base in the nanopores of zeolite-Y. MnII(Hsal- hrz)/Y, which showed excellent catalytic property in oxidation with various sulfide compounds including important drugs such as adrafinil and modafinil, using hydroperoxide-urea (UHP) as oxidant. Thioanisole conversion was high (98%).

Keywords: Heterogeneous catalyst, sulfoxidation, adrafinil, modafinil, zeotite, hydrazone.

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Article Details

VOLUME: 16
ISSUE: 7
Year: 2019
Page: [541 - 549]
Pages: 9
DOI: 10.2174/1570178615666180622123944
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