ipso-Nitration of Arylboronic Acids with Copper Nitrate and Trifluoroacetic Acid

Author(s): Zhu-Qing Wang, Meng-Ping Guo*, Yong-Ju Wen, Xiu-Li Shen, Mei-Yun Lv, Xiu-Ling Zhou.

Journal Name: Letters in Organic Chemistry

Volume 15 , Issue 10 , 2018

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Abstract:

An efficient and novel nitrating reagent has been developed for ipso-nitration of arylboronic acids. By using inexpensive and commercially available Cu(NO3)2/CF3COOH as nitrating reagent, various nitroarenes are produced in moderate to excellent yields (51-96%). Advantages of this procedure are the operational simplicity and no need of extra catalyst.

Keywords: Arylboronic acids, Cu(NO3)2/CF3COOH as nitrating reagent, ipso-Nitration, nitroarenes, catalyst-free.

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Article Details

VOLUME: 15
ISSUE: 10
Year: 2018
Page: [891 - 894]
Pages: 4
DOI: 10.2174/1570178615666180413122942
Price: $65

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