Hydrosilylation of olefins catalyzed by Cp2TiCl2/Sm (Cp = cyclopentadienyl) under solventfree
conditions has been investigated. The mole ratio of Cp2TiCl2/Sm has some influence on the catalytic
properties, and the best Cp2TiCl2/Sm ratio for the catalytic hydrosilylation is 1/2. By using this
catalytic system, hydrogenation products were also detected in the final reaction mixtures.
Keywords: Alkene, catalytic, hydrosilylation, samarium, solvent-free, titanocene.
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