Hydrosilylation of Olefins with the Cp2TiCl2/Sm Catalytic System

Author(s): Xiaoling Yang, Ying Bai*, Jiayun Li, Yu Liu, Jiajian Peng*.

Journal Name: Letters in Organic Chemistry

Volume 15 , Issue 12 , 2018

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Abstract:

Hydrosilylation of olefins catalyzed by Cp2TiCl2/Sm (Cp = cyclopentadienyl) under solventfree conditions has been investigated. The mole ratio of Cp2TiCl2/Sm has some influence on the catalytic properties, and the best Cp2TiCl2/Sm ratio for the catalytic hydrosilylation is 1/2. By using this catalytic system, hydrogenation products were also detected in the final reaction mixtures.

Keywords: Alkene, catalytic, hydrosilylation, samarium, solvent-free, titanocene.

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Article Details

VOLUME: 15
ISSUE: 12
Year: 2018
Page: [1042 - 1045]
Pages: 4
DOI: 10.2174/1570178615666180212160523
Price: $65

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