Abstract
An efficient protocol for the intermolecular amidoselenation of alkenes with diphenyl diselenides and acetonitrile has been developed that affords a series of β-amidoselenides in high yields under mild conditions. The preliminary experimental results support the involvement of active benzyl radical species, and a radical pathway was therefore proposed for the reaction.
Keywords: Alkenes, amidoselenation, radical, difunctionalization, β-amido-selenides, transformation.
Current Organic Chemistry
Title:Amidoselenation of Alkenes Yielding the β-Amido-selenides through a Radical Pathway
Volume: 22 Issue: 6
Author(s): Feng Zhao, Ting Sun, Zhenhua Liu, Kai Sun, Chong Zhang and Xin Wang*
Affiliation:
- College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang 455000,China
Keywords: Alkenes, amidoselenation, radical, difunctionalization, β-amido-selenides, transformation.
Abstract: An efficient protocol for the intermolecular amidoselenation of alkenes with diphenyl diselenides and acetonitrile has been developed that affords a series of β-amidoselenides in high yields under mild conditions. The preliminary experimental results support the involvement of active benzyl radical species, and a radical pathway was therefore proposed for the reaction.
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Cite this article as:
Zhao Feng , Sun Ting , Liu Zhenhua , Sun Kai , Zhang Chong and Wang Xin *, Amidoselenation of Alkenes Yielding the β-Amido-selenides through a Radical Pathway, Current Organic Chemistry 2018; 22 (6) . https://dx.doi.org/10.2174/2215081107666180123144818
DOI https://dx.doi.org/10.2174/2215081107666180123144818 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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