Abstract
Background: Binary metal oxides, such as spinel nickel cobaltite (NiCo2O4), are attractive pseudocapacitive materials in electrochemical supercapacitors because they have higher theoretical capacitance than carbonaceous materials, and higher electronic conductivity than conventional monometal oxides. However, their practical pseudocapacitive performance is dramatically hindered by traditional electrode assembly technologies, through which extremely high internal resistances are generated at supplementary interfaces within nanostructured binary metal oxides and between binary metal oxides/current collector.
Methods: Here, we develop polymer-binder-free hybrid electrodes by employing Ni nanotube arrays as 3D current collectors for the loading of electroactive NiCo2O4 nanosheets (Ni/NiCo2O4 nanotube array).
Results: As a result of the remarkably enhanced electronic conductivity and ion diffusion, the Ni/NiCo2O4 nanotube array electrodes exhibit a specific capacitance of as high as ~753 F g-1 at a scan rate of 5 mV s-1 and rate performance, in addition to a long-term cycling stability.
Conclusion: The outstanding performance makes the Ni/NiCo2O4 nanotube array to be an efficacious power source electrode in a wide range of applications.
Keywords: Binary metal oxides, NiCo2O4, Ni nanotube arrays, 3D architecture, supercapacitor, energy storage.
Graphical Abstract
Call for Papers in Thematic Issues
Role of nanomaterials in fabrication of coatings, Machining and Joining
The application of nanoscience has brought about a revolution in the field of mechanical engineering by providing novel materials, boosting manufacturing processes, and generating cutting-edge products. The purpose of this special issue is to investigate the enormous impact that nanoscience has had on mechanical engineering, with a particular emphasis on ...read more
Advanced Inorganic Nanocomposites and Their Emerging Applications
This special issue collection will highlight developments on the recent trends about the synthesis of metal oxides, nanoclusters, biomaterials, 2D nanomaterials, nanocrystals, nanocomposites, etc. and their applications in electrochemical systems, tissue regeneration, energy storage and harvesting, sensors, etc. The novelty of the methods in the chemical synthesis and their characterizations, ...read more
Applicability of Nanotechnology for Performance Enhancement of Clean Energy Technologies
Population growth, industrialization, and improvement in living quality would lead to further increase in energy demand in near future. Regarding the disadvantages of fossil fuels such as fluctuations in their price, high emissions of greenhouse gases and restriction of their sources, it is crucial to use and exploit alternative energy ...read more
Graphene and 2D Materials for Energy Storage and Conversion
This thematic issue will discuss the recent advances in graphene-based nanomaterials for different energy technologies. Graphene possesses a high surface area, and stable structure and exhibits many interesting electronic, optical, and mechanical properties due to its 2D crystal structure. Graphene is of both fundamental interest and suitable for a wide ...read more
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