Abstract
Background: Many studies on the electrochemical properties of electrospun nanofiber in lithium-ion batteries (LIBs) have been performed. To the best of our knowledge, no work has yet summarized the use of electrospun one-dimensional materials as anode materials and also assessed the influence of this unique morphology on the properties of LIBs properties. This review describes recent advances in the synthesis and characterization of a variety of 1D multifunctional oxides, oxide composites and oxide-carbon composites electrospun nanofibers used as anodes in LIBs, which provide both excellent capacity and high mechanical integrity.
Method: Oxide, oxide composite and oxide-carbon composite electrospun nanofibers are reviewed as anodes in LIBs. For each material type, we report on the structural and electrochemical properties, and also discuss how to control the structures of the resulting materials and improve the electrochemical performance characteristics (e.g., capacity, cycle life, and rate capability). We apply correlation method and step-to-step focusing method to present the references. Results: 176 papers were included in the review; 6 tables and 7 figures are shown in this paper. The manuscript is divided into 5 parts. For the electrospinning parameters of nanofibers, different conditions were compared, such as polymer, solvent, polymer concentration, voltage level, and tip-tocollector distance. The processing conditions of electrospun oxides nanofibers are also discussed, including the oxide precursor, solvent, voltage level, calcination temperature/heating rate. The performance of electrospun oxide nanofibers as electrodes in LIBs are summarized including metal oxide- metal, metal oxide- metal oxide, and metal oxide-carbon composites. Conclusion: The findings of this review confirm that prepared electrospun electrode materials tend to form 3D interconnected networks, which can enhance electrochemical activities of electrode materials via facilitating electronic/ionic transfers. The electrochemical performance of electrospun MexOy nanofibers depends on process parameters and also the component structure such as metalembedded, carbon coated/doped, and metal oxide hybrid material. However, the electrospun MexOy nanofibers require additional development before commercial application. To utilize the described materials as effective anodes in commercial LIBs, especially for electric vehicle applications, additional research work is required.Keywords: Electrode, electrospining, lithium-ion battery, metal oxide, nanofiber.
Graphical Abstract
Call for Papers in Thematic Issues
Role of nanomaterials in fabrication of coatings, Machining and Joining
The application of nanoscience has brought about a revolution in the field of mechanical engineering by providing novel materials, boosting manufacturing processes, and generating cutting-edge products. The purpose of this special issue is to investigate the enormous impact that nanoscience has had on mechanical engineering, with a particular emphasis on ...read more
Advanced Inorganic Nanocomposites and Their Emerging Applications
This special issue collection will highlight developments on the recent trends about the synthesis of metal oxides, nanoclusters, biomaterials, 2D nanomaterials, nanocrystals, nanocomposites, etc. and their applications in electrochemical systems, tissue regeneration, energy storage and harvesting, sensors, etc. The novelty of the methods in the chemical synthesis and their characterizations, ...read more
Applicability of Nanotechnology for Performance Enhancement of Clean Energy Technologies
Population growth, industrialization, and improvement in living quality would lead to further increase in energy demand in near future. Regarding the disadvantages of fossil fuels such as fluctuations in their price, high emissions of greenhouse gases and restriction of their sources, it is crucial to use and exploit alternative energy ...read more
Graphene and 2D Materials for Energy Storage and Conversion
This thematic issue will discuss the recent advances in graphene-based nanomaterials for different energy technologies. Graphene possesses a high surface area, and stable structure and exhibits many interesting electronic, optical, and mechanical properties due to its 2D crystal structure. Graphene is of both fundamental interest and suitable for a wide ...read more
Related Books
Nanoscale Field Effect Transistors: Emerging Applications
Nanoelectronics Devices: Design, Materials, and Applications Part II
Nanoelectronics Devices: Design, Materials, and Applications (Part I)
Role of Nanotechnology in Cancer Therapy
Synthesis and Applications of Semiconductor Nanostructures
Pathways to Green Nanomaterials: Plants as Raw Materials, Reducing Agents and Hosts
Applications of Nanomaterials in Medical Procedures and Treatments
Synthesis of Nanomaterials
Nanobiotechnology: Principles and Applications
Bio-Inspired Nanotechnology
32
2