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Current Green Chemistry

Editor-in-Chief

ISSN (Print): 2213-3461
ISSN (Online): 2213-347X

Research Article

A Convenient One-Pot Aqueous Phase Synthesis and Properties of Naphtho[ e]bis[1,3]oxazines

Author(s): Bijoy P. Mathew, Neha Batra and Mahendra Nath*

Volume 3, Issue 4, 2016

Page: [360 - 365] Pages: 6

DOI: 10.2174/2213346104666170215152404

Price: $65

Abstract

Background: A simple and eco-friendly synthetic protocol for synthesizing naphtho[ e]bis[1,3]oxazines in good yields has been developed by using one-pot three-component Mannich-type condensation cyclization reaction of various dihydroxynaphthalenes with primary amines and formaldehyde in water at 80-90°C.

Methods: The chemical structures of synthesized monomers were confirmed by IR, 1H-NMR, mass and elemental analysis.

Result: Some of these compounds exhibited promising processing window for polymerization according to their differential scanning calorimetric analysis.

Keywords: Eco-friendly method, Mannich-type reaction, naphtho[e]bis[1, 3]oxazines, one-pot synthesis, polynaphthoxazines, water.

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