Abstract
Polyoxometalates (POMs) and their hybrid systems are green and efficient catalysts which have found a wide range of application, due to their outstanding properties such as high thermal stability, Redox potential, strong Bronsted acidity, non-corrosive nature and sensitivity to electricity and light. They are able to catalyze various organic reactions as well as being involved in photocatalytic processes. In this review, we try to highlight the recent advances (2009-2015) in the applications of POMs both in their actual structural forms and in the form of hybrid/ composite as catalysts in divergent chemical processes including, organic synthesis, biomass conversion, petrochemical processes, photocatalytic degradation and fuel cell.
Keywords: HPAs, HPA, POMs, PMOs, catalysis, organic synthesis, biomass, fuel cell.
Graphical Abstract
Call for Papers in Thematic Issues
Advances of Heterocyclic Chemistry with Pesticide Activity
Global food safety and security will continue to be a global concern for the next 50 years and beyond. Plant diseases have had a significant impact on food safety and security throughout the entire food chain, from primary production to consumption. While conventional chemical pesticides have been traditionally used for ...read more
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This research area combines theoretical computation and screening with machine learning for the design of covalent/metal organic framework-based catalysts, bridging the disciplines of organic chemistry, physical chemistry, computational chemistry, materials science, and machine learning. It covers several critical aspects: designing and synthesizing organic catalysts for improved performance, applying computational methods ...read more
Carbohydrates conversion in biofuels and bioproducts
Biomass pretreatment, hydrolysis, and saccharification of carbohydrates, and sugars bioconversion in biofuels and bioproducts within a biorefinery framework. Carbohydrates derived from woody biomass, agricultural wastes, algae, sewage sludge, or any other lignocellulosic feedstock are included in this issue. Simulation, techno-economic analysis, and life cycle analysis of a biorefinery process are ...read more
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
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