LIESST Effect in Fe(II) 1,2,4-Triazole Chains

Author(s): Yann Garcia, Franz Renz, Philipp Gütlich.

Journal Name: Current Inorganic Chemistry (Discontinued)

Volume 6 , Issue 1 , 2016

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Abstract:

One-dimensional Fe(II) chains with 1,2,4-triazole as bridging ligands present the LIESST effect; i.e. their spin state switched from low-spin to high-spin after light irradiation at low temperature. This account summarizes the findings in this area of photomagnetism where 57Fe Mössbauer spectroscopy was used as a primary detection tool of the LIESST effect.

Keywords: 1D chains, iron, LIESST effect, metastable state, photomagnetism, spin crossover.

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Article Details

VOLUME: 6
ISSUE: 1
Year: 2016
Page: [4 - 9]
Pages: 6
DOI: 10.2174/1877944105666150910195707

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