A Study on the Deoxygenation of Phosphine Oxides by Different Silane Derivatives

Author(s): Tamara Kovacs, Anita Urbanics, Flora Csatlos, Judith Binder, Astrid Falk, Frank Uhlig, Gyorgy Keglevich.

Journal Name: Current Organic Synthesis

Volume 13 , Issue 1 , 2016

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Abstract:

The deoxygenation of phosphine oxides was studied on two model reactions, on the reduction of 3- methyl-1-phenyl-3-phospholene 1-oxide and triphenylphosphine oxide using an aralkylsilane, arylsilanes, diarylsilanes, a disiloxane, a polysiloxane and a disilane under solvent-free, thermal or microwave-assisted conditions. The deoxygenations were optimized, and the reactivity of the silanes was evaluated. User-friendly accomplishments were elaborated.

Keywords: Deoxygenation, Microwave, Phosphine oxides, Phosphines, Silanes, User friendly reagents.

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Article Details

VOLUME: 13
ISSUE: 1
Year: 2016
Page: [148 - 153]
Pages: 6
DOI: 10.2174/1570179412666150817222349

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