Total Synthesis of Xestoaminol C from D-Glucose

Author(s): Hanmanth R. Vulupala, Yasodakrishna Sajja, Rajashaker Bantu, Lingaiah Nagarapu.

Journal Name: Current Organic Chemistry

Volume 19 , Issue 20 , 2015

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Abstract:

A convenient and practical approach for the total synthesis of Xestoaminol C has been accomplished with 16.43% overall yield from commercially available D-glucose. The synthesis involves SN2 type centre inversion with azido group, Staudinger reaction, Wittig olefination and Pearlman’s catalytic hydrogenation.

Keywords: Staudinger reaction, Wittig olefination, oxidative cleavage, hydrogenation, D-glucose.

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Article Details

VOLUME: 19
ISSUE: 20
Year: 2015
Page: [2040 - 2045]
Pages: 6
DOI: 10.2174/1385272819666150730214151
Price: $58

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