Chirality of Hypervalent Chalcogenuranes

Author(s): Jozef Drabowicz, Jacek Chrzanowski, Dorota Krasowska, Adrian Zajac.

Journal Name: Current Organic Chemistry

Volume 20 , Issue 2 , 2016

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Abstract:

This review presents synthetic procedures applied to the preparation of chiral (mainly optically active) hypervalent chalcogenuranes. The stereoisomerization mechanisms of hypervalent derivatives of sulfur, selenium and tellurium and their selected interconversions are also presented.

Keywords: Hypervalency, chirality, sulfurane, selenurane, tellurane, Berry pseudorotation, turnstile rotation.

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Article Details

VOLUME: 20
ISSUE: 2
Year: 2016
Page: [146 - 154]
Pages: 9
DOI: 10.2174/1385272819666150724233459
Price: $58

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