Developments of Corey-Chaykovsky in Organic Reactions and Total Synthesis of Natural Products

Author(s): Majid M. Heravi , Shima Asadi , Niousha Nazari , Boshra Malekzadeh Lashkariani .

Journal Name: Current Organic Synthesis

Volume 13 , Issue 3 , 2016

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Abstract:

The reactions of sulfur ylides with carbonyl, olefin or imine compounds named as the Corey- Chaykovsky, provide oxiranes, cyclopropane or aziridine, respectively. In this report, we try to introduce this important name reaction and highlight a comprehensive overview on the applications of this useful reaction in synthetic organic chemistry and total synthesis of natural products.

Keywords: Corey-Chaykovsky, epoxidation, dimethylsulfoxonium methylide, dimethylsulfonium methylide, organic and total synthesis.

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Article Details

VOLUME: 13
ISSUE: 3
Year: 2016
Page: [308 - 333]
Pages: 26
DOI: 10.2174/1570179412666150710182304
Price: $58

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