Phosphine Ligands for the Hydroformylation of Allyl Alcohol

Author(s): Wilhelm Jan Tic, Antoni Zoltanski.

Journal Name: Current Catalysis

Volume 4 , Issue 3 , 2015

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Abstract:

Allyl alcohol has become an attractive feedstock for commercial organic synthesis after the development and technical-scale implementation of cost-effective methods for its manufacturing. Its major applications include hydroformylation to obtain C4 aldehyde alcohols in the presence of catalytic rhodium complexes, followed by their hydrogenation to 1,4-butanediol as the principal product. The development of phosphine ligands that are used in the hydroformylation reaction and commercial processes to obtain 1,4-butanediol from allyl alcohol are discussed.

Keywords: Allyl alcohol, phosphine ligands, rhodium catalyst, hydroformylation, 1, 4-butanediol preparation.

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Article Details

VOLUME: 4
ISSUE: 3
Year: 2015
Page: [155 - 165]
Pages: 11
DOI: 10.2174/2211544704666150710175104
Price: $58

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