A Clean and Practical Catalyst free Synthesis of Keto and Aldoximes as well as the Beckmann Rearrangement by using Ethyl Lactate as an Environmentally Benign Medium

Author(s): Yunyun Liu, Weijiang Wen.

Journal Name: Current Green Chemistry

Volume 2 , Issue 4 , 2015

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Abstract:

Ethyl lactate, a bio-based nontoxic solvent has been found as a medium for the general synthesis of keto- and aldoximes under catalyst-free conditions. The synthesis of amides via Fe-catalyzed Beckmann rearrangement of the ketoxime has also been realized in the same green medium.

Keywords: Aldoximes, bio-based medium, ethy lactate, ketoximes, sustainable synthesis.

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Article Details

VOLUME: 2
ISSUE: 4
Year: 2015
Page: [399 - 402]
Pages: 4
DOI: 10.2174/2213346102666150702155424
Price: $58

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