Enynal/Enynone: A Safe and Practical Carbenoid Precursor

Author(s): Jun Ma, Li Zhang, Shifa Zhu.

Journal Name: Current Organic Chemistry

Volume 20 , Issue 1 , 2016

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Abstract:

Recently, non-diazo carbene precursors have attracted more and more interest because of the apparent safety reason. As one of the most reliable and useful non-diazo carbenoid precursors, enynal/enynone can give rise to furyl- or pyrylium-carbene, which has be applied in a wide range of carbene-transfer reactions, such as cyclopropanation, C-H and X-H insertion, 1,3-dipolar cycloaddition and ylide formation reaction.

Keywords: Carbene, enynal, enynone, cyclopropanation, C-H insertion, X-H insertion.

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Article Details

VOLUME: 20
ISSUE: 1
Year: 2016
Page: [102 - 118]
Pages: 17
DOI: 10.2174/1385272819666150608222517

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