Insertion of Arynes into the π-Bond Giving [2+2] Cycloaddition-type Adducts

Author(s): Hideto Miyabe.

Journal Name: Current Organic Chemistry

Volume 19 , Issue 13 , 2015

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Graphical Abstract:


The studies on the reaction of arynes with the π-bond are limited, although synthetic chemistry using aryne has attracted substantial attention. This review highlights the insertion of arynes into the π-bond giving the formal [2+2] cycloaddition-type adducts. In this review, the synthetic organic reactions involving the [2+2]-type reactions of arynes with the carbon-carbon double bond, the carbon-heteroatom double bond and the heteroatomheteroatom double bond are summarized.

Keywords: Aryne, benzyne, insertion, [2+2] cycloaddition.

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Article Details

Year: 2015
Page: [1222 - 1241]
Pages: 20
DOI: 10.2174/1385272819666150505190020
Price: $58

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