Natural Phosphate-supported Palladium: A Highly Efficient and Recyclable Catalyst for the Suzuki-Miyaura Coupling Under Microwave Irradiation

Author(s): Ayoub Hassine, Mohamed Bouhrara, Said Sebti, Abderrahim Solhy, Remi Mahfouz, Denis Luart, Christophe Len, Aziz Fihri.

Journal Name: Current Organic Chemistry

Volume 18 , Issue 24 , 2014

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Abstract:

This report explores Suzuki-Miyaura coupling under microwave irradiation, using a new generation of catalyst that is based on natural phosphate (NP) impregnated by palladium. This catalyst was prepared by the treatment of natural phosphate with bis(benzonitrile)palladium(II) chloride in acetone at room temperature. The catalyst displayed high catalytic activity for the Suzuki-Miyaura coupling of aryl bromides and chlorides with aryl boronic acids in pure water and with the use of microwave irradiation. The low-cost and availability of the solid support, mild reaction conditions, high yields of desired products, recyclability of the catalyst and short reaction times are the notable features of these methods.

Keywords: Green chemistry, heterogeneous catalysis, microwave irradiation, natural phosphate, supported Pd catalysts, suzuki-miyaura reactions.

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Article Details

VOLUME: 18
ISSUE: 24
Year: 2014
Page: [3141 - 3148]
Pages: 8
DOI: 10.2174/1385272819666141117234222
Price: $58

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