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Current Microwave Chemistry
ISSN (Print): 2213-3356
ISSN (Online): 2213-3364
VOLUME: 1
ISSUE: 2
DOI: 10.2174/2213335601666140630165348      Price:  $58









Bismuth Nitrate Catalyzed Microwave Assisted Aza-Diels Alder Reaction for Synthesis of Bicyclo[2,2,2]-Octanones Scaffold

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Author(s): Ram Naresh Yadav, Ashwini Bobbala, Sunena Chandra and Bimal K. Banik
Pages 94-97 (4)
Abstract:
Bismuth nitrate-catalyzed microwave-assisted one-pot three components Aza-Diels-Alder reaction has been investigated. This method has been used for an efficient synthesis of 2-azabicyclo[2,2,2] cyclooctanones.
Graphical Abstract:
Keywords:
Alkaloids, aza-Diels-Alder, azabicycle, bismuth nitrate, cycloadducts, diastereoselectivity, dienophile, endo/exo, heterocycles, in situ, keto-enol tautomerization, Lewis acid, microwave chemistry, natural product, one-pot chemistry.
Affiliation:
Department of Chemistry, The University of Texas Pan American, 1201 West University Drive, Edinburg, Texas 78539, USA.