Current Microwave Chemistry

Bimal K. Banik
Vice President of Research & Education Development
Community Health Systems of South Texas (CHSST)
Edinburg, TX
USA

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Bismuth Nitrate Catalyzed Microwave Assisted Aza-Diels Alder Reaction for Synthesis of Bicyclo[2,2,2]-Octanones Scaffold

Author(s): Ram Naresh Yadav, Ashwini Bobbala, Sunena Chandra and Bimal K. Banik

Affiliation: Department of Chemistry, The University of Texas Pan American, 1201 West University Drive, Edinburg, Texas 78539, USA.

Keywords: Alkaloids, aza-Diels-Alder, azabicycle, bismuth nitrate, cycloadducts, diastereoselectivity, dienophile, endo/exo, heterocycles, in situ, keto-enol tautomerization, Lewis acid, microwave chemistry, natural product, one-pot chemistry.

Graphical Abstract:


Abstract:

Bismuth nitrate-catalyzed microwave-assisted one-pot three components Aza-Diels-Alder reaction has been investigated. This method has been used for an efficient synthesis of 2-azabicyclo[2,2,2] cyclooctanones.

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Article Details

VOLUME: 1
ISSUE: 2
Page: [94 - 97]
Pages: 4
DOI: 10.2174/2213335601666140630165348