Bismuth Nitrate Catalyzed Microwave Assisted Aza-Diels Alder Reaction for Synthesis of Bicyclo[2,2,2]-Octanones Scaffold

Author(s): Ram Naresh Yadav, Ashwini Bobbala, Sunena Chandra, Bimal K. Banik.

Journal Name:Current Microwave Chemistry

Volume 1 , Issue 2 , 2014

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Abstract:

Bismuth nitrate-catalyzed microwave-assisted one-pot three components Aza-Diels-Alder reaction has been investigated. This method has been used for an efficient synthesis of 2-azabicyclo[2,2,2] cyclooctanones.

Keywords: Alkaloids, aza-Diels-Alder, azabicycle, bismuth nitrate, cycloadducts, diastereoselectivity, dienophile, endo/exo, heterocycles, in situ, keto-enol tautomerization, Lewis acid, microwave chemistry, natural product, one-pot chemistry.

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Article Details

VOLUME: 1
ISSUE: 2
Year: 2014
Page: [94 - 97]
Pages: 4
DOI: 10.2174/2213335601666140630165348