Current Organic Chemistry

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Porous Organic Molecular Cages: from Preparation to Applications

Author(s): Ming Xiong, Huimin Ding, Bijian Li, Tailin Zhou, Cheng Wang.

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Abstract:

The design and synthesis of molecular container compounds is playing an important role in host–guest chemistry. Porous organic molecular cages (OMCs) represent an exciting type of container-like compounds and have attracted intensive attention in the past few decades. These materials are constructed through covalent bonds and can be synthesized in reasonable yield by making use of dynamic covalent chemistry. Furthermore, they can pack to form crystalline materials with void spaces, thus showing potential applications in gas absorption and molecular separation. In this article, we highlight the state-of-the-art development in the synthesis, functionalization and application of OMCs.

Keywords: Dynamic covalent chemistry, gas absorption and separation, molecular container compounds, molecular reaction flask, molecular recognition, porous solid materials.

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Article Details

VOLUME: 18
ISSUE: 15
Year: 2014
Page: [1965 - 1972]
Pages: 8
DOI: 10.2174/1385272819666140514004934
Price: $58