Organoselenium Chemistry: Between Synthesis and Biochemistry

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The use of organoselenium reagents as catalysts is a common thread that runs through the chapters of this book, introducing important aspects of the modern organoselenium chemistry: organocatalysis, ...
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Organoselenium Compounds as Precursor of Radicals

Pp. 94-119 (26)

Jarosław Lewkowski

Abstract

Radical reactions with the participation of selenium compounds have been described here in the point of view of the source of selenium radicals. Consequently, the following groups have been reviewed: alkyl phenyl selenides, acyl phenyl selenides, imidoyl phenyl selenides, benzeneselenol and other selenides as the source of radicals.

The chapter covers the literature from early 90s until 2012.

Keywords:

Radicals, Selenides, Stannanes, Silanes, Diselenides, Addition, Cyclization, Coupling, Stereoselectivity, Regioselectivity.

Affiliation:

University of Łódź, Faculty of Chemistry, Department of Organic Chemistry, Tamka 12; 91-403 Łódź, Poland