Organoselenium Chemistry: Between Synthesis and Biochemistry

Indexed in: Book Citation Index, Science Edition, EBSCO.

The use of organoselenium reagents as catalysts is a common thread that runs through the chapters of this book, introducing important aspects of the modern organoselenium chemistry: organocatalysis, ...
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Electrophilic Selenium Reagents: Addition Reactions to Double Bonds and Selenocyclizations

Pp. 8-60 (53)

Jacek Ścianowski and Zbigniew Rafiński

Abstract

Addition reactions of electrophilic selenium reagents to the double bonds, selenocyclizations, and their stereochemical aspects are described. The synthesis of electrophilic organoselenium reagents, including optically active examples, the formation of new carbon-oxygen, carbon-nitrogen, carbon-carbon bonds, and applications in the synthesis of heterocycles are presented.

Keywords:

Addition, Electrophiles, Selenides, Oxyselenenylation, Azaselenenylation, Carboselenenylation, Asymmetric Synthesis, Cyclofunctionalization, Heterocycles, Stereoselectivity.

Affiliation:

Department of Organic Chemistry, Faculty of Chemistry, Nicolaus Copernicus University, 7 Gagarin Street, 87-100 Torun, Poland