Current Organic Synthesis

Eduardo A. Castro
Universidad Nacional de La Plata
Buenos Aires
Argentina

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Higher Efficiently Conversion of Heterocyclic Aryl Nitroalkenes to Ketones

Author(s): Dushu Huang, Jin-Gang Yu, Wei Liu, Yunhui Long and Jing Wang

Affiliation: College of chemistry and Chemical Engineering, Central South University, Changsha, Hunan 410083, P.R. China and College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, P.R. China.

Keywords: Heterocyclic aryl nitroalkenes, Fe-FeCl3-CH3COOH system, ketones, Nef reaction, reductive hydrolysis.

Graphical Abstract:


Abstract:

Ketones were prepared by a modified Nef reaction using heterocyclic aryl nitroalkenes to react in a Fe-FeCl3-CH3COOH mixture with higher yield over 50% in sharp contrast with in Fe-HCl mixture with lower yield less than 30%, thus it’s cost-saving and relative environment friendly.

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Article Details

VOLUME: 11
ISSUE: 6
Page: [907 - 910]
Pages: 4
DOI: 10.2174/1570179411666140424232227