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Current Organic Synthesis
ISSN (Print): 1570-1794
ISSN (Online): 1875-6271
Epub Full Text Article
DOI: 10.2174/1570179411666140424232227      Price:  $95









Higher Efficiently Conversion of Heterocyclic Aryl Nitroalkenes to Ketones

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Author(s): Dushu Huang, Jin-Gang Yu, Wei Liu, Yunhui Long and Jing Wang
Abstract:
Ketones were prepared by a modified Nef reaction using heterocyclic aryl nitroalkenes to react in a Fe-FeCl3-CH3COOH mixture with higher yield over 50% in sharp contrast with in Fe-HCl mixture with lower yield less than 30%, thus it’s cost-saving and relative environment friendly.
Keywords:
Ketones, Nef reaction, Fe-FeCl3-CH3COOH system, reductive hydrolysis, heterocyclic aryl nitroalkenes
Affiliation:
College of Science, Honghe University, Mengzi 661100, P. R. China.