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Current Organic Synthesis
ISSN (Print): 1570-1794
ISSN (Online): 1875-6271
VOLUME: 11
ISSUE: 6
DOI: 10.2174/1570179411666140424232227      Price:  $58









Higher Efficiently Conversion of Heterocyclic Aryl Nitroalkenes to Ketones

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Author(s): Dushu Huang, Jin-Gang Yu, Wei Liu, Yunhui Long and Jing Wang
Pages 907-910 (4)
Abstract:
Ketones were prepared by a modified Nef reaction using heterocyclic aryl nitroalkenes to react in a Fe-FeCl3-CH3COOH mixture with higher yield over 50% in sharp contrast with in Fe-HCl mixture with lower yield less than 30%, thus it’s cost-saving and relative environment friendly.
Graphical Abstract:
Keywords:
Heterocyclic aryl nitroalkenes, Fe-FeCl3-CH3COOH system, ketones, Nef reaction, reductive hydrolysis.
Affiliation:
College of chemistry and Chemical Engineering, Central South University, Changsha, Hunan 410083, P.R. China and College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, P.R. China.