Synthesis of Asymmetric Diaryl Sulfides by SNAr Reaction of Substituted Nitrobenzene with Aryl Disulfides

Author(s): Naoki Enjo , Rong Lu , Tetsuo Miyakoshi .

Journal Name: Current Organic Synthesis

Volume 10 , Issue 6 , 2013

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Abstract:

A series of sulfides was successfully synthesized from nitroarenes by SNAr reaction via elimination of a nitro or phenylsulfonyl group. The SNAr reaction mechanism is found to depend on the position and type of substituents, and the effect of two-electron withdrawing groups was also examined.

Keywords: Sulfide, SNAr reaction, nitro group, aryl disulfide.

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Article Details

VOLUME: 10
ISSUE: 6
Year: 2013
Page: [961 - 968]
Pages: 8
DOI: 10.2174/157017941006140206105221
Price: $58

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