Novel Benzo-15-crown-5/C60 Dyads with Different Chains: Synthesis and Complexation Properties

Author(s): Biqiong Hong, Fafu Yang, Jinqi Ye, Hongyu Guo, Xiaoyun Yan.

Journal Name: Letters in Organic Chemistry

Volume 11 , Issue 1 , 2014

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Abstract:

Using benzo-15-crown-5 derivatives as starting materials, two novel benzo-15-crown-5/C60 dyads with different linking chains were designed and synthesized in good yields by 1,3-dipolar cycloaddition of azomethine ylide generated in situ from aldehyde and sarcosine tied to C60. It was found that their UV-Vis absorption spectra could be regulated hypsochromically by metal ions complexation. The long and soft linking chain was favorable for cooperate interaction of crown ether unit and C60 unit.

Keywords: C60, benzo-15-crown-5, chain, synthesis, complexation.

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Article Details

VOLUME: 11
ISSUE: 1
Year: 2014
Page: [2 - 5]
Pages: 4
DOI: 10.2174/157017861101140113155347

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