Synthesis and Functionalization of Corroles. An Insight on Their Nonlinear Optical Absorption Properties
Carla I.M. Santos, Joana F.B. Barata, Mário J.F. Calvete, Luís S.H.P. Vale, Danilo Dini, Moreno Meneghetti, Maria G.P.M.S. Neves, Maria A.F. Faustino, Augusto C. Tomé and José A.S. Cavaleiro
Affiliation: Department of Chemistry, University of Rome “La Sapienza”, 00185 Rome, Italy.
Keywords: Corroles, cycloaddition reactions, functionalization, nanosecond pulse, optical limiting, reverse saturable absorption.
The development of efficient synthetic methodologies and post-functionalization procedures gave access to a wide variety of
new corrole derivatives with potential applications in different areas. This paper reviews the preparation of meso-triaarylcorroles and
their functionalization, namely via cycloaddition transformations, and describes the nonlinear optical (NLO) properties of a series of
metal-free and gallium corroles with different peripheral substituents. The corroles studied were the free base 5,10,15-tris-
(pentafluorophenyl)corrole, the corresponding gallium(III) complex and adducts obtained from 1,3-dipolar cycloaddition reaction. Correlations
between the structure and the NLO effect of optical power limiting were attempted in our comparative analysis. The present contribution
is one of the first reports on the effect of reverse saturable absorption in the visible spectrum generated by corrole-based complexes.
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