Highly Efficient and Selective Addition of Hydroxylamine to Nitriles in Ionic Liquids

Author(s): Attila Voros, Zoltan Baan, Geza Timari, Istvan Hermecz, Peter Mizsey, Zoltan Finta.

Journal Name:Current Organic Synthesis

Volume 11 , Issue 5 , 2014

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Abstract:

The solvent effect of different imidazolium, phosphonium and quaternary ammonium based ionic liquids was studied for the synthesis of amidoximes, demonstrating enhanced selectivity when using IL’s as the reaction medium.

Keywords: Amidoxime, benzonitriles, green chemistry, hydroxylamine, ionic liquid, selective synthesis.

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Article Details

VOLUME: 11
ISSUE: 5
Year: 2014
Page: [751 - 756]
Pages: 6
DOI: 10.2174/15701794113106660082
Price: $58