Halogen Exchange via a Halogenation of Diaryliodonium Salts with Cuprous Halide

Author(s): Jian Li, Li Liu, Dong Ding, Jiang-tao Sun.

Journal Name: Letters in Organic Chemistry

Volume 10 , Issue 8 , 2013

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Abstract:

An efficient halogenation reaction has been developed with diaryliodonium salts and cuprous halides. Various diaryliodonium salts 1 could perform the reaction with readily available CuBr or CuCl in CH3CN at 80°C, assembling bromoarenes or chloroarenes in up to 92% yields. This provides us a method for the transformation from iodoarenes to other haloarenes.

Keywords: Diaryliodonium salts, Halogenation, Cuprous halide, Aromatic halides, Iodoarenes.

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Article Details

VOLUME: 10
ISSUE: 8
Year: 2013
Page: [541 - 548]
Pages: 8
DOI: 10.2174/15701786113109990011

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