Iodine Mediated Addition of Trialkylamines to Dimethyl Acetylenedicarboxylate

Author(s): Quanping Wu, Hui-Fang Liu, Yue Zhang, Shiyu Shen, Song Xue.

Journal Name: Letters in Organic Chemistry

Volume 10 , Issue 9 , 2013

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Abstract:

Addition reaction of tertiary amines to dimethyl acetylenedicarboxylate mediated by molecular iodine is described. The trialkylamines afford dealkylative adducts in moderate to good yields. Amines containing an aryl group react sluggishly in low yields with a loss of alkyl group.

Keywords: Dimethyl acetylenedicarboxylate, molecular iodine, addition reaction, trialkylamines.

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Article Details

VOLUME: 10
ISSUE: 9
Year: 2013
Page: [617 - 621]
Pages: 5
DOI: 10.2174/15701786113109990027
Price: $65

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