Synthesis of Novel Phthalocyanine and Using It as a Heterogeneous, Reusable and Efficient Catalyst for the Oxidation of Alcohols

Author(s): Mohammad Ali Zolfigol, Ali Reza Pourali, Sami Sajjadifar, Shohreh Farahmand.

Journal Name:Current Catalysis

Volume 2 , Issue 2 , 2013

Abstract:

3-Nitrophthalic anhydride was reacted with urea and cobalt salt in nitrobenzene under N2(g) at 185°C producing cobalt-tetranitrophthalocyanine (CoTNP) was produced. Also, in this work, Cobalt-tetraaminophthalocyanine (CoTAP) was produced by reduction of CoTNP caused by Sodium borohydride under N2(g). Cobalt-tetraaminophthalocyanine-bondedpolymer (CoTAPBP) was produced by reaction of Cobalt-tetraaminophthalocyanine with chloromethylpolystyrene (CMPS).

Keywords: Phthalocyanines, tetraaminometallophthalocyanine, CoTAP-bonded-polymer, CoTAPBP, oxidation of alcohols.

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Article Details

VOLUME: 2
ISSUE: 2
Year: 2013
Page: [151 - 158]
Pages: 8
DOI: 10.2174/2211544711302020009
Price: $58