Synthesis of Novel Phthalocyanine and Using It as a Heterogeneous, Reusable and Efficient Catalyst for the Oxidation of Alcohols
Mohammad Ali Zolfigol,
Ali Reza Pourali,
3-Nitrophthalic anhydride was reacted with urea and cobalt salt in nitrobenzene under N2(g) at 185°C producing
cobalt-tetranitrophthalocyanine (CoTNP) was produced. Also, in this work, Cobalt-tetraaminophthalocyanine (CoTAP) was
produced by reduction of CoTNP caused by Sodium borohydride under N2(g). Cobalt-tetraaminophthalocyanine-bondedpolymer
(CoTAPBP) was produced by reaction of Cobalt-tetraaminophthalocyanine with chloromethylpolystyrene (CMPS).
Keywords: Phthalocyanines, tetraaminometallophthalocyanine, CoTAP-bonded-polymer, CoTAPBP, oxidation of alcohols.
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