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Current Organic Chemistry

Editor-in-Chief

ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Synthesis of a Rigid Fused Porphyrin-Phthalocyanine Hetero-Dyad with Two Different Metals

Author(s): Mario J.F. Calvete, Joao P.C. Tome and Jose A.S. Cavaleiro

Volume 17, Issue 10, 2013

Page: [1103 - 1107] Pages: 5

DOI: 10.2174/1385272811317100010

Price: $65

Abstract

The synthesis and characterization of the first rigid fused porphyrin-phthalocyanine hetero-dyad with two different metals is reported; was based on porphyrin’s dienophile features in Diels–Alder reactions. This synthetic procedure represents a new approach for the synthesis of extended systems based on tetrapyrrolic macrocycles.

Keywords: Bimetallic systems, Diels-Alder reactions, Extended heterocyclic systems, Porphyrins, Phthalocyanines.


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