The synthesis and characterization of the first rigid fused porphyrin-phthalocyanine hetero-dyad with two different
metals is reported; was based on porphyrin’s dienophile features in Diels–Alder reactions. This synthetic procedure
represents a new approach for the synthesis of extended systems based on tetrapyrrolic macrocycles.
Keywords: Bimetallic systems, Diels-Alder reactions, Extended heterocyclic systems, Porphyrins, Phthalocyanines.
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