Glycosylation Methods in Oligosaccharide Synthesis
Pp. 238-295 (58)
Ana T. Carmona, Antonio J. Moreno-Vargas and Inmaculada Robina
In this part other procedures of glycosylation reactions by direct activation are
presented. We will focus on the n-pentenyl glycoside, the O-alkylation and the
trichloroacetimidate methods. The use of glycosyl phosphates and glycals in glycosidation
reactions are also discussed. Updated examples of these glycosylation methodologies
involving total synthesis of oligosaccharides and related compounds are considered.
Glycosylation, oligosaccharides, pentenyl glycosides,
trichloroacetimidates, glycosyl phosphates, glycals, glycosyl donors, glycosyl
acceptors, n-pentenyl 1, 2-orthoesters, NPG, NPOE, thioglycosides, orthogonal
glycosylation, chemoselective glycosidations.
Department of Organic Chemistry, Faculty of Chemistry, University of Seville, P.O. Box 1203, E-41071 Seville, Spain.